1-Oxa-3-azapentalen-2-ones as Precursors of cis-2-Amino Alcohols: Synthesis from Propargyl Alcohols, CO2, and Amines Using an Intramolecular Amidoalkylation Reaction of Oxazolidin-2-ones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-07

AUTHORS

N. B. Chernysheva, A. A. Bogolyubov, V. V. Nesterov, M. Yu. Antipin, V. V. Semenov

ABSTRACT

The reaction of 5-methyl-5-(4-methyl-3-pentenyl)-4-methylene-1,3-dioxolan-2-one with primary amines gives the corresponding 4-hydroxy-4-methyloxazolidin-2-ones. These undergo an intramolecular amidoalkylation reaction to form 1-oxa-3-azapentalen-2-ones which are potential precursors of cyclopentanyl cis-2-amino alcohols.

PAGES

925-936

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1026154623110

DOI

http://dx.doi.org/10.1023/a:1026154623110

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031414508


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