Synthesis, Physicochemical Properties, and Structure of Heterocyclic β-Aminovinyl Ketones and Related Copper(II) Complex View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-10

AUTHORS

A. S. Antsyshkina, G. G. Sadikov, O. Yu. Korshunov, E. L. Anpilova, A. S. Bicherov, V. S. Sergienko, I. E. Uflyand, A. D. Garnovskii

ABSTRACT

Heterocyclic β-aminovinyl ketones (HL) and the copper complex CuL2 are synthesized and studied by IR and 1H NMR spectroscopies. The crystal structure of one of the tautomeric HL molecules is determined by X-ray diffraction analysis. The crystals are triclinic: a = 9.261(6) Å, b = 9.448(6) Å, c = 11.310(5) Å, α = 96.74(5)°, β = 99.46(5)°, γ = 93.60(5)°, space group P. The compound has the form of a ketoamine tautomer. The structure contains intramolecular and intermolecular hydrogen bonds. The latter link the molecules into the center-symmetric dimers. More... »

PAGES

724-731

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1026080318102

DOI

http://dx.doi.org/10.1023/a:1026080318102

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016478172


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