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          "alternateName": "Federal State Unitary Enterprise Design and Technology Bureau \u201cTekhnolog\u201d at, St. Petersburg State Technological Institute, 198013, St. Petersburg, Russia", 
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    "description": "Abstract1,2-Dinitroguanidine is a product of nitroguanidine nitration with nitric acid and its mixtures with sulfuric acid and oleum. It is a diacid (pKa 1.11, \u223c11.5) and at the same time a weak base undergoing protonation at the nitrogen of the amino group (pKBH+ -5.81). The decomposition kinetics of 1,2-dinitroguanidine was studied by spectrophotometric method both in acid and alkaline media, and the mechanism of the process was assumed. In the media of high acidity (Ho > -8) the 1,2-dinitroguanidine suffers reversible denitration into nitroguanidine. At lower acidity its conjugate acid or molecular form undergoes hydrolysis yielding nitrourea. Monoanion of 1,2-dinitroguanidine in a weak acid or in an alkali is hydrolyzed into N,N'-dinitrourea. The reaction of 1,2-dinitroguanidine with alkali in alcohol provides its salts, with nitrogen-containing bases form both salts and derivatives of 2-nitroguanidine. The treatment of 1,2-dinitroguanidine with haloalkanes results in its N-alkylated products.", 
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        "name": "Russian Journal of Organic Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
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        "volumeNumber": "39"
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    ], 
    "keywords": [
      "nitrogen-containing bases", 
      "N\u2032-dinitrourea", 
      "dinitroguanidine", 
      "alkaline medium", 
      "amino groups", 
      "conjugate acid", 
      "nitric acid", 
      "sulfuric acid", 
      "undergoes hydrolysis", 
      "high acidity", 
      "weak acids", 
      "spectrophotometric method", 
      "low acidity", 
      "weak base", 
      "decomposition kinetics", 
      "salt", 
      "acid", 
      "acidity", 
      "alkali", 
      "monoanion", 
      "diacids", 
      "protonation", 
      "nitrourea", 
      "synthesis", 
      "products", 
      "nitroguanidine", 
      "derivatives", 
      "reaction", 
      "denitration", 
      "nitration", 
      "hydrolysis", 
      "mixture", 
      "kinetics", 
      "Olea", 
      "alcohol", 
      "nitrogen", 
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      "method", 
      "base", 
      "group", 
      "basis", 
      "same time", 
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    ], 
    "name": "Synthesis and Some Properties of 1,2-Dinitroguanidine", 
    "pagination": "501-512", 
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