Binuclear Cu(II) and Ni(II) Complexes with Schiff Bases—the Products of Condensation of Amino Alcohols with 2-Phenylhydrazone 1-Phenylbutane-1,2,3-Trione: Synthesis and Magnetic ... View Full Text


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Article Info

DATE

2003-09

AUTHORS

E. V. Dontsova, V. V. Lukov, V. A. Kogan, L. D. Popov

ABSTRACT

The binuclear complexes of Cu2+ and Ni2+ with a new ligand system obtained through condensation of amino alcohols with 2-phenylhydrazone 1-phenylbutane-1,2,3-trione were synthesized. The compositions and structures of ligands and complexes were determined using elemental analysis, IR and NMR spectroscopy and magnetochemistry. The nickel complexes were found to be diamagnetic; in the copper complexes, substantial antiferromagnetic exchange interaction was observed (for Cu2+ complexes with n = 2 and 3, 2J is equal to –396 and –393 cm–1, respectively). The structure of the exchange fragment \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$O \backslash / Cu Cu O \backslash /$$ \end{document} is discussed. More... »

PAGES

639-642

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1025611727728

DOI

http://dx.doi.org/10.1023/a:1025611727728

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051144168


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