Regiospecific CO substitution in (μ-H)Ru3(μ3− η3-CHCHCMe)(CO)9 by 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione(bpcd). X-ray structure of (μ-H)Ru3(μ3−η3-CHCHCMe)(CO)7(bpcd)⋅MeOH View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-09

AUTHORS

Chun-Gu Xia, Simon G. Bott, Michael G. Richmond

ABSTRACT

The triruthenium cluster (μ -H)Ru3(μ 3−η3-CHCHCMe)(CO)9 reacts with the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) in the presence of Me3NO to afford (μ -H)Ru3(μ 3−η 3-CHCHCMe)(CO)7(bpcd) in moderate yield. This new cluster has been isolated and characterized in solution by IR and NMR (1H, 31P) spectroscopies, and the solid-state structure has been established by X-ray crystallography. (μ -H)Ru3(μ 3−η 3-CHCHCMe)(CO)7(bpcd) ⋅ MeOH crystallizes in the triclinic space group P, a = 11.2426(8) Å, b = 11.7141(8) Å, c = 16.195(1) Å, α = 102.041(5)°, β = 95.128(5)°, γ = 102.553(6)°, V = 2008.4(3) Å3, Z = 2, dcalc. = 1.733 g/cm3; R = 0.0488, Rw = 0.0546 for 2212 observed reflections with I > 3σ (I). The X-ray structure reveals that the bpcd ligand is bound exclusively to the Ru3 core at the ruthenium center coordinated by the terminal CH unit of the π -allylic μ 3−η 3-CHCHCMe moiety. More... »

PAGES

681-687

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1025389408857

DOI

http://dx.doi.org/10.1023/a:1025389408857

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019915415


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