How can the metal affect the proton transfer to the dihydrides [{P(CH2CH2PPh2)3}MH2] (M = Fe, Ru, Os)? A low-temperature electronic ... View Full Text


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Article Info

DATE

2003-05

AUTHORS

E. I. Gutsul, N. V. Belkova, G. M. Babakhina, L. M. Epstein, E. S. Shubina, C. Bianchini, M. Peruzzini, F. Zanobini

ABSTRACT

According to low-temperature UV-Vis spectroscopy data, the two-step protonation of iron subgroup metal hydrides [{P(CH2CH2PPh2)3}MH2] (M = Fe, Ru, Os) with p-nitrophenol includes the formation of ion pairs stabilized by a hydrogen bond between the cationic dihydrogen complex and the phenolate anion. The trend of the extent of proton transfer appeared to be aperiodic, FeI ≪ OsI < RuI, in contrast to the previously obtained sequence of the proton-acceptor capacity of the hydride ligand, which increases down the group. More... »

PAGES

1204-1206

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1024786030162

DOI

http://dx.doi.org/10.1023/a:1024786030162

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049039181


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