Alkyl-substituted 2,6-dioxadiazolylpyridines as selective extractants for trivalent actinides View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-06

AUTHORS

M. Weigl, U. Müllich, A Geist, K. Gompper, T. Zevaco, H. Stephan

ABSTRACT

2,6-di(3-alkyl-1,2,4-oxadiazol-5-yl)pyridines, 2,6-di(5-alkyl-1,3,4-oxadiazol-2-yl)pyridines, and 2,6-di(5-alkyl-1,2,4-oxadiazol-3-yl)pyridines were synthesized and tested for their americium(III)-europium(III) selectivity by liquid-liquid extraction. 0.02M solutions of the compounds extract americium(III) 2-bromohexanoates as monosolvates, AmA3B, from solutions of pH 2, with an americium(III)-europium(III) separation factor of up to 23. Decreasing the alkyl chain length (butyl < ethyl < methyl) or the polarity of the diluent (chlorobenzene < toluene < tert.-butyl benzene) increased both americium(III) distribution ratio and americium(III)-europium(III) separation factor. More... »

PAGES

403-412

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1024531228330

DOI

http://dx.doi.org/10.1023/a:1024531228330

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030871370


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