Acid-Base properties of MgCuAl mixed oxides View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-04

AUTHORS

S. Casenave, H. Martinez, C. Guimon, A. Auroux, V. Hulea, E. Dumitriu

ABSTRACT

MgCuAl layered double hydroxides (LDHs) with a hydrotalcite like structure containing different proportions of Mg2+ and Cu2+ cations have been prepared. Thermogravimetry and X-ray diffraction data indicated that the transformation of LDH into mixed oxides is effective after calcination at 723 K, irrespective of the composition. The acid-base properties of these mixed oxides have been investigated using adsorption microcalorimetry and X-ray photoelectron spectroscopy with NH3 (for acidity) and SO2 (for basicity) as probe molecules. Their catalytic behaviour for the conversion of cyclohexanol has been tested. The acid-base properties and the selectivity of catalysts has been related to their composition. More... »

PAGES

191-198

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1023980005672

DOI

http://dx.doi.org/10.1023/a:1023980005672

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1020539165


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