Ontology type: schema:ScholarlyArticle
2003-03
AUTHORSO. A. Gerasko, A. V. Virovets, D. G. Samsonenko, A. A. Tripol"skaya, V. P. Fedin, D. Fenske
ABSTRACTCrystals of the {[Sr4(H2O)12(NO3)4](C36H36N24O12)}(NO3)4·3H2O and {[Sr2(H2O)12][Sr(H2O)3(NO3)2]2(C48H48N32O16)}(NO3)4·8H2O were prepared by slow concentration of aqueous solutions containing strontium nitrate and macrocyclic cavitands, viz., cucurbit[6]uril and cucurbit[8]uril ([C6H6N4O2]n, n = 6 and 8), respectively. According to the results of X-ray diffraction analysis, the crystal structures of these supramolecular compounds are built from polymeric chains, which consist of the alternating cucurbit[n]uril molecules and Sr2+ cations linked through the bridging aqua ligands and nitrate anions. The supramolecular compound of cucurbit[8]uril provides the first example of compounds in which this macrocycle is bound to metal aqua complexes. More... »
PAGES585-593
http://scigraph.springernature.com/pub.10.1023/a:1023942303190
DOIhttp://dx.doi.org/10.1023/a:1023942303190
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