Conformational Composition of 2,5-Disubstituted 1,3,2-Dioxaborinanes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-03

AUTHORS

V. V. Kuznetsov, A. N. Novikov, I. S. Rublev, P. Yu. Markolenko

ABSTRACT

We have used 1H NMR spectra and also MM+ and AM1 calculation methods to show that the conformational equilibrium of 2,5-disubstituted 1,3,2-dioxaborinane molecules, including two sofa forms, is shifted toward the equatorial conformer. We have established the values of ΔG0 for a number of substituents on the C(5) ring atom.

PAGES

379-385

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1023931314095

DOI

http://dx.doi.org/10.1023/a:1023931314095

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047240344


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