Photochromic and Thermochromic Spiropyrans. 22. Spiropyrans of the 4-Oxo-3,4-dihydro-3H-1,3-benzoxazine Series Containing π-Accepting Substituents at Position 8' View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-03

AUTHORS

A. O. Bulanov, B. B. Safoklov, B. S. Luk'yanov, V. V. Tkachev, V. I. Minkin, S. M. Aldoshin, Yu. S. Alekseenko

ABSTRACT

New spiropyrans of the benzoxazinone series were synthesized by modification of the formyl group in compounds containing an asymmetric spiro carbon atom. It was shown that 1H NMR identification of the spiropyrans containing π-accepting hydrazone substituents must be conducted at elevated temperatures by following the presence of and degree of subsequent “recovery”. According to X-ray crystallographic analysis, crystal solvates can form, depending on the solvent used for crystallization of the hydrazones of the spiropyrans. More... »

PAGES

315-317

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1023906608643

DOI

http://dx.doi.org/10.1023/a:1023906608643

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044246784


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