C(methyl)–H ⋅ ⋅ ⋅ π(aryl) Interaction Stabilizing Molecular Conformation. X-Ray Crystal Structure of an Inclusion Compound of a Nonprotic Host ... View Full Text


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Article Info

DATE

2003-06

AUTHORS

Ingeborg Csöregh, Stefan Finge, Edwin Weber

ABSTRACT

In the cocrystal formation of a nonprotic polar (host) molecule (1) with nitromethane (guest) several weak, but directional, intermolecular interactions have vital importance. The endo conformation of the (N)-xylene group of the polycyclic succinimide-based host 1 is stabilized by a CmethylH ⋅⋅⋅ π interaction [C ⋅⋅⋅ π /H ⋅⋅⋅ π distances are 3.554(7)/2.57 Å, the CH ⋅⋅⋅ π angle is 159○], and the crystal packing is governed by dipole–dipole type interhost (C)O ⋅⋅⋅ C(O) connection [C ⋅⋅⋅ O3.000(5) Å and More... »

PAGES

241-246

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1023898027469

DOI

http://dx.doi.org/10.1023/a:1023898027469

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016038852


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