Reaction of bis(dimethoxyphosphino)dimethylhydrazine (dmpdmh) with PhCCo3(CO)9: synthesis and X-ray characterization of the dmpdmh-bridged polymorphs of PhCCo3(CO)7[(MeO)2PN(Me)N(Me)P(OMe)2] View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-05

AUTHORS

Simon G. Bott, Jian Cheng Wang, Michael G. Richmond

ABSTRACT

The tricobalt cluster PhCCo3(CO)9 reacts with the bis(phosphanyl)hydrazine ligand bis(dimethoxyphosphino)dimethylhydrazine (dmpdmh) to give the monosubstituted cluster [PhCCo3(CO)8]2(dmpdmh) and the disubstituted cluster PhCCo3(CO)7(dmpdmh) as the major products. This latter cluster contains a bridging dmpdmh ligand. Both IR and NMR spectroscopies (31P and 1H) have been employed in the solution characterization of these two clusters. The solid-state structure of PhCCo3(CO)7(dmpdmh) was unequivocally established by X-ray diffraction analysis, which has revealed the presence of two different polymorphs for this particular cluster. The first polymorph crystallizes in the monoclinic space group P21/n, a = 9.7127(7) Å, b = 17.025(2) Å,c = 16.894(1) Å, β = 96.245(5)°, V = 2777.0(4) Å3, Z = 4, and dcalc = 1.689 g/cm3; while the second polymorph crystallizes in the orthorhombic space group Pbca, a = 16.925(2) Å, b = 16.208(2) Å, c = 20.541(3) Å, V = 5635(1) Å3, Z = 8, and dcalc = 1.665 g/cm3. More... »

PAGES

401-407

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1022420410672

DOI

http://dx.doi.org/10.1023/a:1022420410672

DIMENSIONS

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