Solid‐State Combustion in Mechanically Activated SHS Systems. I. Effect of Activation Time on Process Parameters and Combustion Product Composition View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-01

AUTHORS

M. A. Korchagin, T. F. Grigor'eva, B. B. Bokhonov, M. R. Sharafutdinov, A. P. Barinova, N. Z. Lyakhov

ABSTRACT

The factors responsible for the transition from reagent interaction involving a liquid phase in ordinary SHS powder mixtures to solid‐state combustion after preliminary activation of these mixtures in an energy‐intensive planetary mill were studied for Ni + 13 wt. % Al and Ni + 45 wt. % Ti compositions. The dependences of the burning rate and temperature on the duration and conditions of mechanical activation were determined. It is found that the occurrence of solid‐state SHS in a powdermixture is due to the formation of “laminated composites,” in which the reagents are ground to ultrafine size, the area of their contact increases severalfold, and the concentration of nonequilibrium defects is high. In activated samples, heat release proceeds in several stages and at lower temperature than in powder mixtures. More... »

PAGES

43-50

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1022145201911

DOI

http://dx.doi.org/10.1023/a:1022145201911

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040676554


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0915", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Interdisciplinary Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Siberian Division, Russian Academy of Sciences, Institute of Solid\u2010State Chemistry and Mechanochemistry, 630128, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Siberian Division, Russian Academy of Sciences, Institute of Solid\u2010State Chemistry and Mechanochemistry, 630128, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Korchagin", 
        "givenName": "M. A.", 
        "id": "sg:person.015025417455.23", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015025417455.23"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Division, Russian Academy of Sciences, Institute of Solid\u2010State Chemistry and Mechanochemistry, 630128, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Siberian Division, Russian Academy of Sciences, Institute of Solid\u2010State Chemistry and Mechanochemistry, 630128, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Grigor'eva", 
        "givenName": "T. F.", 
        "id": "sg:person.013354216505.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013354216505.16"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Division, Russian Academy of Sciences, Institute of Solid\u2010State Chemistry and Mechanochemistry, 630128, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Siberian Division, Russian Academy of Sciences, Institute of Solid\u2010State Chemistry and Mechanochemistry, 630128, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bokhonov", 
        "givenName": "B. B.", 
        "id": "sg:person.013054306634.87", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013054306634.87"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Division, Russian Academy of Sciences, Institute of Solid\u2010State Chemistry and Mechanochemistry, 630128, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Siberian Division, Russian Academy of Sciences, Institute of Solid\u2010State Chemistry and Mechanochemistry, 630128, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sharafutdinov", 
        "givenName": "M. R.", 
        "id": "sg:person.013337157617.51", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013337157617.51"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Division, Russian Academy of Sciences, Institute of Solid\u2010State Chemistry and Mechanochemistry, 630128, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Siberian Division, Russian Academy of Sciences, Institute of Solid\u2010State Chemistry and Mechanochemistry, 630128, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Barinova", 
        "givenName": "A. P.", 
        "id": "sg:person.010423067557.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010423067557.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Division, Russian Academy of Sciences, Institute of Solid\u2010State Chemistry and Mechanochemistry, 630128, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Siberian Division, Russian Academy of Sciences, Institute of Solid\u2010State Chemistry and Mechanochemistry, 630128, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lyakhov", 
        "givenName": "N. Z.", 
        "id": "sg:person.014576700037.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014576700037.15"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02699359", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003121893", 
          "https://doi.org/10.1007/bf02699359"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02672695", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000953279", 
          "https://doi.org/10.1007/bf02672695"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02672741", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041995757", 
          "https://doi.org/10.1007/bf02672741"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2003-01", 
    "datePublishedReg": "2003-01-01", 
    "description": "The factors responsible for the transition from reagent interaction involving a liquid phase in ordinary SHS powder mixtures to solid\u2010state combustion after preliminary activation of these mixtures in an energy\u2010intensive planetary mill were studied for Ni + 13 wt. % Al and Ni + 45 wt. % Ti compositions. The dependences of the burning rate and temperature on the duration and conditions of mechanical activation were determined. It is found that the occurrence of solid\u2010state SHS in a powdermixture is due to the formation of \u201claminated composites,\u201d in which the reagents are ground to ultrafine size, the area of their contact increases severalfold, and the concentration of nonequilibrium defects is high. In activated samples, heat release proceeds in several stages and at lower temperature than in powder mixtures.", 
    "genre": "article", 
    "id": "sg:pub.10.1023/a:1022145201911", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1049027", 
        "issn": [
          "0010-5082", 
          "1573-8345"
        ], 
        "name": "Combustion, Explosion, and Shock Waves", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "39"
      }
    ], 
    "keywords": [
      "powder mixtures", 
      "solid-state combustion", 
      "combustion product composition", 
      "state combustion", 
      "process parameters", 
      "SHS systems", 
      "planetary mill", 
      "ultrafine size", 
      "mechanical activation", 
      "liquid phase", 
      "Ti composition", 
      "combustion", 
      "product composition", 
      "nonequilibrium defects", 
      "low temperatures", 
      "temperature", 
      "composites", 
      "preliminary activation", 
      "Ni", 
      "wt", 
      "activation time", 
      "mixture", 
      "reagent interaction", 
      "mill", 
      "SHS", 
      "composition", 
      "parameters", 
      "phase", 
      "conditions", 
      "al", 
      "dependence", 
      "size", 
      "system", 
      "defects", 
      "formation", 
      "transition", 
      "concentration", 
      "effect", 
      "rate", 
      "area", 
      "time", 
      "samples", 
      "proceeds", 
      "interaction", 
      "stage", 
      "reagents", 
      "factors", 
      "occurrence", 
      "duration", 
      "severalfold", 
      "activation", 
      "ordinary SHS powder mixtures", 
      "SHS powder mixtures", 
      "energy\u2010intensive planetary mill", 
      "solid\u2010state SHS", 
      "powdermixture", 
      "contact increases severalfold", 
      "increases severalfold", 
      "heat release proceeds", 
      "release proceeds", 
      "Mechanically Activated SHS Systems", 
      "Activated SHS Systems"
    ], 
    "name": "Solid\u2010State Combustion in Mechanically Activated SHS Systems. I. Effect of Activation Time on Process Parameters and Combustion Product Composition", 
    "pagination": "43-50", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1040676554"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/a:1022145201911"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/a:1022145201911", 
      "https://app.dimensions.ai/details/publication/pub.1040676554"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-12-01T19:14", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211201/entities/gbq_results/article/article_374.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1023/a:1022145201911"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1022145201911'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1022145201911'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1022145201911'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1022145201911'


 

This table displays all metadata directly associated to this object as RDF triples.

167 TRIPLES      22 PREDICATES      91 URIs      80 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/a:1022145201911 schema:about anzsrc-for:09
2 anzsrc-for:0915
3 schema:author Na64a928efca5408185561107cb5c31e9
4 schema:citation sg:pub.10.1007/bf02672695
5 sg:pub.10.1007/bf02672741
6 sg:pub.10.1007/bf02699359
7 schema:datePublished 2003-01
8 schema:datePublishedReg 2003-01-01
9 schema:description The factors responsible for the transition from reagent interaction involving a liquid phase in ordinary SHS powder mixtures to solid‐state combustion after preliminary activation of these mixtures in an energy‐intensive planetary mill were studied for Ni + 13 wt. % Al and Ni + 45 wt. % Ti compositions. The dependences of the burning rate and temperature on the duration and conditions of mechanical activation were determined. It is found that the occurrence of solid‐state SHS in a powdermixture is due to the formation of “laminated composites,” in which the reagents are ground to ultrafine size, the area of their contact increases severalfold, and the concentration of nonequilibrium defects is high. In activated samples, heat release proceeds in several stages and at lower temperature than in powder mixtures.
10 schema:genre article
11 schema:inLanguage en
12 schema:isAccessibleForFree false
13 schema:isPartOf N82eb584abf7b44b093d73592aaa3b3df
14 Ndb2c401caec840bfb13cdcf89a61e9f6
15 sg:journal.1049027
16 schema:keywords Activated SHS Systems
17 Mechanically Activated SHS Systems
18 Ni
19 SHS
20 SHS powder mixtures
21 SHS systems
22 Ti composition
23 activation
24 activation time
25 al
26 area
27 combustion
28 combustion product composition
29 composites
30 composition
31 concentration
32 conditions
33 contact increases severalfold
34 defects
35 dependence
36 duration
37 effect
38 energy‐intensive planetary mill
39 factors
40 formation
41 heat release proceeds
42 increases severalfold
43 interaction
44 liquid phase
45 low temperatures
46 mechanical activation
47 mill
48 mixture
49 nonequilibrium defects
50 occurrence
51 ordinary SHS powder mixtures
52 parameters
53 phase
54 planetary mill
55 powder mixtures
56 powdermixture
57 preliminary activation
58 proceeds
59 process parameters
60 product composition
61 rate
62 reagent interaction
63 reagents
64 release proceeds
65 samples
66 severalfold
67 size
68 solid-state combustion
69 solid‐state SHS
70 stage
71 state combustion
72 system
73 temperature
74 time
75 transition
76 ultrafine size
77 wt
78 schema:name Solid‐State Combustion in Mechanically Activated SHS Systems. I. Effect of Activation Time on Process Parameters and Combustion Product Composition
79 schema:pagination 43-50
80 schema:productId Nbfc9b03837ff4945836cd72f9eb4e939
81 Nfb95a57de7564c7a90f4c4ad4dc496d1
82 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040676554
83 https://doi.org/10.1023/a:1022145201911
84 schema:sdDatePublished 2021-12-01T19:14
85 schema:sdLicense https://scigraph.springernature.com/explorer/license/
86 schema:sdPublisher N9bb263e98c754a419bde71b808141ac3
87 schema:url https://doi.org/10.1023/a:1022145201911
88 sgo:license sg:explorer/license/
89 sgo:sdDataset articles
90 rdf:type schema:ScholarlyArticle
91 N00cdd04970d54dea8b707b3883b9e75b rdf:first sg:person.014576700037.15
92 rdf:rest rdf:nil
93 N3210968ab99e426aae79be1a5ac03df3 rdf:first sg:person.010423067557.96
94 rdf:rest N00cdd04970d54dea8b707b3883b9e75b
95 N35dd5678b2a54271b0c4be0ba2f0c785 rdf:first sg:person.013354216505.16
96 rdf:rest Nb743f67cde284b9a8159754fd73679cd
97 N46b87d549be946a2b02bd24252921980 rdf:first sg:person.013337157617.51
98 rdf:rest N3210968ab99e426aae79be1a5ac03df3
99 N82eb584abf7b44b093d73592aaa3b3df schema:issueNumber 1
100 rdf:type schema:PublicationIssue
101 N9bb263e98c754a419bde71b808141ac3 schema:name Springer Nature - SN SciGraph project
102 rdf:type schema:Organization
103 Na64a928efca5408185561107cb5c31e9 rdf:first sg:person.015025417455.23
104 rdf:rest N35dd5678b2a54271b0c4be0ba2f0c785
105 Nb743f67cde284b9a8159754fd73679cd rdf:first sg:person.013054306634.87
106 rdf:rest N46b87d549be946a2b02bd24252921980
107 Nbfc9b03837ff4945836cd72f9eb4e939 schema:name doi
108 schema:value 10.1023/a:1022145201911
109 rdf:type schema:PropertyValue
110 Ndb2c401caec840bfb13cdcf89a61e9f6 schema:volumeNumber 39
111 rdf:type schema:PublicationVolume
112 Nfb95a57de7564c7a90f4c4ad4dc496d1 schema:name dimensions_id
113 schema:value pub.1040676554
114 rdf:type schema:PropertyValue
115 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
116 schema:name Engineering
117 rdf:type schema:DefinedTerm
118 anzsrc-for:0915 schema:inDefinedTermSet anzsrc-for:
119 schema:name Interdisciplinary Engineering
120 rdf:type schema:DefinedTerm
121 sg:journal.1049027 schema:issn 0010-5082
122 1573-8345
123 schema:name Combustion, Explosion, and Shock Waves
124 schema:publisher Springer Nature
125 rdf:type schema:Periodical
126 sg:person.010423067557.96 schema:affiliation grid-institutes:grid.415877.8
127 schema:familyName Barinova
128 schema:givenName A. P.
129 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010423067557.96
130 rdf:type schema:Person
131 sg:person.013054306634.87 schema:affiliation grid-institutes:grid.415877.8
132 schema:familyName Bokhonov
133 schema:givenName B. B.
134 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013054306634.87
135 rdf:type schema:Person
136 sg:person.013337157617.51 schema:affiliation grid-institutes:grid.415877.8
137 schema:familyName Sharafutdinov
138 schema:givenName M. R.
139 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013337157617.51
140 rdf:type schema:Person
141 sg:person.013354216505.16 schema:affiliation grid-institutes:grid.415877.8
142 schema:familyName Grigor'eva
143 schema:givenName T. F.
144 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013354216505.16
145 rdf:type schema:Person
146 sg:person.014576700037.15 schema:affiliation grid-institutes:grid.415877.8
147 schema:familyName Lyakhov
148 schema:givenName N. Z.
149 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014576700037.15
150 rdf:type schema:Person
151 sg:person.015025417455.23 schema:affiliation grid-institutes:grid.415877.8
152 schema:familyName Korchagin
153 schema:givenName M. A.
154 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015025417455.23
155 rdf:type schema:Person
156 sg:pub.10.1007/bf02672695 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000953279
157 https://doi.org/10.1007/bf02672695
158 rdf:type schema:CreativeWork
159 sg:pub.10.1007/bf02672741 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041995757
160 https://doi.org/10.1007/bf02672741
161 rdf:type schema:CreativeWork
162 sg:pub.10.1007/bf02699359 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003121893
163 https://doi.org/10.1007/bf02699359
164 rdf:type schema:CreativeWork
165 grid-institutes:grid.415877.8 schema:alternateName Siberian Division, Russian Academy of Sciences, Institute of Solid‐State Chemistry and Mechanochemistry, 630128, Novosibirsk
166 schema:name Siberian Division, Russian Academy of Sciences, Institute of Solid‐State Chemistry and Mechanochemistry, 630128, Novosibirsk
167 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...