Structure and Magnetic Properties of Solid Solutions of Molecular Magnetics Based on Ni(II) and Co(II) Complexes with Nitroxyl Radicals View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-07

AUTHORS

E. Yu. Fursova, V. N. Ikorskii, G. V. Romanenko, V. A. Reznikov, Yu. G. Shvedenkov, V. I. Ovcharenko

ABSTRACT

Ni(II) and Co(II) complexes with deprotonated paramagnetic enaminoketones 4‐(3′,3′,3′‐trifluorine‐2′‐oxopropylidene)‐ 2,2,5,5‐tetramethyl‐3‐imidazolidine‐1‐oxyl (L) and 4‐(3′,3′,3′‐trifluorine‐1′‐chlorine‐2′‐oxopropylidene)‐2,2,5,5‐tetramethyl‐3‐imidazolidine‐1‐oxy‐l (L1) and alcohols are shown to form continuous solid solutions NixCo1-xL2(C2H5OH)2 and NixCo1-xL21(CH3OH)2. Single crystal X‐ray diffraction analysis showed that concentration variation practically does not affect the structural characteristics of the solid solutions. Distinguishing features if the magnetic behavior of NixCo1-xL2 · (C2H5OH)2 and NixCo1-xL21(CH3OH)2 are the antiferromagnetic interaction of the moments of the nickel and cobalt sublattices inside the polymeric layers and the antiferromagnetic nature of interlayer interaction of the magnetic moments. More... »

PAGES

656-663

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1022056705815

DOI

http://dx.doi.org/10.1023/a:1022056705815

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034194048


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomographic Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk", 
            "Novosibirsk State University, Novosibirsk", 
            "Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fursova", 
        "givenName": "E. Yu.", 
        "id": "sg:person.07501453217.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07501453217.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomographic Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk", 
            "Novosibirsk State University, Novosibirsk", 
            "Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ikorskii", 
        "givenName": "V. N.", 
        "id": "sg:person.012705501235.78", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012705501235.78"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomographic Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk", 
            "Novosibirsk State University, Novosibirsk", 
            "Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Romanenko", 
        "givenName": "G. V.", 
        "id": "sg:person.0664032236.40", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664032236.40"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomographic Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk", 
            "Novosibirsk State University, Novosibirsk", 
            "Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Reznikov", 
        "givenName": "V. A.", 
        "id": "sg:person.0604152251.53", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0604152251.53"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomographic Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk", 
            "Novosibirsk State University, Novosibirsk", 
            "Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shvedenkov", 
        "givenName": "Yu. G.", 
        "id": "sg:person.011403635127.22", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011403635127.22"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomographic Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk", 
            "Novosibirsk State University, Novosibirsk", 
            "Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ovcharenko", 
        "givenName": "V. I.", 
        "id": "sg:person.0732145436.56", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732145436.56"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2002-07", 
    "datePublishedReg": "2002-07-01", 
    "description": "Ni(II) and Co(II) complexes with deprotonated paramagnetic enaminoketones 4\u2010(3\u2032,3\u2032,3\u2032\u2010trifluorine\u20102\u2032\u2010oxopropylidene)\u2010 2,2,5,5\u2010tetramethyl\u20103\u2010imidazolidine\u20101\u2010oxyl (L) and 4\u2010(3\u2032,3\u2032,3\u2032\u2010trifluorine\u20101\u2032\u2010chlorine\u20102\u2032\u2010oxopropylidene)\u20102,2,5,5\u2010tetramethyl\u20103\u2010imidazolidine\u20101\u2010oxy\u2010l (L1) and alcohols are shown to form continuous solid solutions NixCo1-xL2(C2H5OH)2 and NixCo1-xL21(CH3OH)2. Single crystal X\u2010ray diffraction analysis showed that concentration variation practically does not affect the structural characteristics of the solid solutions. Distinguishing features if the magnetic behavior of NixCo1-xL2 \u00b7 (C2H5OH)2 and NixCo1-xL21(CH3OH)2 are the antiferromagnetic interaction of the moments of the nickel and cobalt sublattices inside the polymeric layers and the antiferromagnetic nature of interlayer interaction of the magnetic moments.", 
    "genre": "article", 
    "id": "sg:pub.10.1023/a:1022056705815", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1135923", 
        "issn": [
          "0022-4766", 
          "2542-0976"
        ], 
        "name": "Journal of Structural Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "43"
      }
    ], 
    "keywords": [
      "single crystal X", 
      "solid solution", 
      "ray diffraction analysis", 
      "crystal X", 
      "molecular magnetics", 
      "polymeric layer", 
      "nitroxyl radicals", 
      "antiferromagnetic interactions", 
      "diffraction analysis", 
      "continuous solid solution", 
      "cobalt sublattice", 
      "antiferromagnetic nature", 
      "magnetic behavior", 
      "magnetic properties", 
      "interlayer interactions", 
      "structural characteristics", 
      "magnetic moment", 
      "complexes", 
      "enaminoketones", 
      "concentration variations", 
      "solution", 
      "radicals", 
      "nickel", 
      "interaction", 
      "alcohol", 
      "properties", 
      "sublattice", 
      "magnetic", 
      "structure", 
      "layer", 
      "nature", 
      "moment", 
      "behavior", 
      "analysis", 
      "characteristics", 
      "variation", 
      "features", 
      "deprotonated paramagnetic enaminoketones", 
      "paramagnetic enaminoketones", 
      "NixCo1-xL2"
    ], 
    "name": "Structure and Magnetic Properties of Solid Solutions of Molecular Magnetics Based on Ni(II) and Co(II) Complexes with Nitroxyl Radicals", 
    "pagination": "656-663", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1034194048"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/a:1022056705815"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/a:1022056705815", 
      "https://app.dimensions.ai/details/publication/pub.1034194048"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-12-01T19:13", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211201/entities/gbq_results/article/article_350.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1023/a:1022056705815"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1022056705815'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1022056705815'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1022056705815'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1022056705815'


 

This table displays all metadata directly associated to this object as RDF triples.

143 TRIPLES      21 PREDICATES      68 URIs      58 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/a:1022056705815 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 anzsrc-for:0303
4 anzsrc-for:0306
5 schema:author Nc2f5bdfca9414f62bf6766fd852b72c1
6 schema:datePublished 2002-07
7 schema:datePublishedReg 2002-07-01
8 schema:description Ni(II) and Co(II) complexes with deprotonated paramagnetic enaminoketones 4‐(3′,3′,3′‐trifluorine‐2′‐oxopropylidene)‐ 2,2,5,5‐tetramethyl‐3‐imidazolidine‐1‐oxyl (L) and 4‐(3′,3′,3′‐trifluorine‐1′‐chlorine‐2′‐oxopropylidene)‐2,2,5,5‐tetramethyl‐3‐imidazolidine‐1‐oxy‐l (L1) and alcohols are shown to form continuous solid solutions NixCo1-xL2(C2H5OH)2 and NixCo1-xL21(CH3OH)2. Single crystal X‐ray diffraction analysis showed that concentration variation practically does not affect the structural characteristics of the solid solutions. Distinguishing features if the magnetic behavior of NixCo1-xL2 · (C2H5OH)2 and NixCo1-xL21(CH3OH)2 are the antiferromagnetic interaction of the moments of the nickel and cobalt sublattices inside the polymeric layers and the antiferromagnetic nature of interlayer interaction of the magnetic moments.
9 schema:genre article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N79a9a436712248d49414a56fb1ea1d6b
13 Nac4af46a9f2c4684b7bdd3e2feb20349
14 sg:journal.1135923
15 schema:keywords NixCo1-xL2
16 alcohol
17 analysis
18 antiferromagnetic interactions
19 antiferromagnetic nature
20 behavior
21 characteristics
22 cobalt sublattice
23 complexes
24 concentration variations
25 continuous solid solution
26 crystal X
27 deprotonated paramagnetic enaminoketones
28 diffraction analysis
29 enaminoketones
30 features
31 interaction
32 interlayer interactions
33 layer
34 magnetic
35 magnetic behavior
36 magnetic moment
37 magnetic properties
38 molecular magnetics
39 moment
40 nature
41 nickel
42 nitroxyl radicals
43 paramagnetic enaminoketones
44 polymeric layer
45 properties
46 radicals
47 ray diffraction analysis
48 single crystal X
49 solid solution
50 solution
51 structural characteristics
52 structure
53 sublattice
54 variation
55 schema:name Structure and Magnetic Properties of Solid Solutions of Molecular Magnetics Based on Ni(II) and Co(II) Complexes with Nitroxyl Radicals
56 schema:pagination 656-663
57 schema:productId N149dfbe3724946fc8cbfd7ef8a98d17d
58 Ne17b6cebad5044fab405469f24684afd
59 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034194048
60 https://doi.org/10.1023/a:1022056705815
61 schema:sdDatePublished 2021-12-01T19:13
62 schema:sdLicense https://scigraph.springernature.com/explorer/license/
63 schema:sdPublisher N8d16e14368574696b3e8f04a1d61899c
64 schema:url https://doi.org/10.1023/a:1022056705815
65 sgo:license sg:explorer/license/
66 sgo:sdDataset articles
67 rdf:type schema:ScholarlyArticle
68 N09556b46ffc9475ca5db7149aa4cce09 rdf:first sg:person.0732145436.56
69 rdf:rest rdf:nil
70 N141141ba4c3445df835e17cfee2c71c8 rdf:first sg:person.0604152251.53
71 rdf:rest Nde9b07c17cd44663a437bf90da8835df
72 N149dfbe3724946fc8cbfd7ef8a98d17d schema:name doi
73 schema:value 10.1023/a:1022056705815
74 rdf:type schema:PropertyValue
75 N1d29ede1b0824e8a8586899598675723 rdf:first sg:person.0664032236.40
76 rdf:rest N141141ba4c3445df835e17cfee2c71c8
77 N54d1b6c6f18f481ba7daf1ed52f973ea rdf:first sg:person.012705501235.78
78 rdf:rest N1d29ede1b0824e8a8586899598675723
79 N79a9a436712248d49414a56fb1ea1d6b schema:issueNumber 4
80 rdf:type schema:PublicationIssue
81 N8d16e14368574696b3e8f04a1d61899c schema:name Springer Nature - SN SciGraph project
82 rdf:type schema:Organization
83 Nac4af46a9f2c4684b7bdd3e2feb20349 schema:volumeNumber 43
84 rdf:type schema:PublicationVolume
85 Nc2f5bdfca9414f62bf6766fd852b72c1 rdf:first sg:person.07501453217.49
86 rdf:rest N54d1b6c6f18f481ba7daf1ed52f973ea
87 Nde9b07c17cd44663a437bf90da8835df rdf:first sg:person.011403635127.22
88 rdf:rest N09556b46ffc9475ca5db7149aa4cce09
89 Ne17b6cebad5044fab405469f24684afd schema:name dimensions_id
90 schema:value pub.1034194048
91 rdf:type schema:PropertyValue
92 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
93 schema:name Chemical Sciences
94 rdf:type schema:DefinedTerm
95 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
96 schema:name Inorganic Chemistry
97 rdf:type schema:DefinedTerm
98 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
99 schema:name Macromolecular and Materials Chemistry
100 rdf:type schema:DefinedTerm
101 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
102 schema:name Physical Chemistry (incl. Structural)
103 rdf:type schema:DefinedTerm
104 sg:journal.1135923 schema:issn 0022-4766
105 2542-0976
106 schema:name Journal of Structural Chemistry
107 schema:publisher Springer Nature
108 rdf:type schema:Periodical
109 sg:person.011403635127.22 schema:affiliation grid-institutes:grid.415877.8
110 schema:familyName Shvedenkov
111 schema:givenName Yu. G.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011403635127.22
113 rdf:type schema:Person
114 sg:person.012705501235.78 schema:affiliation grid-institutes:grid.415877.8
115 schema:familyName Ikorskii
116 schema:givenName V. N.
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012705501235.78
118 rdf:type schema:Person
119 sg:person.0604152251.53 schema:affiliation grid-institutes:grid.415877.8
120 schema:familyName Reznikov
121 schema:givenName V. A.
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0604152251.53
123 rdf:type schema:Person
124 sg:person.0664032236.40 schema:affiliation grid-institutes:grid.415877.8
125 schema:familyName Romanenko
126 schema:givenName G. V.
127 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664032236.40
128 rdf:type schema:Person
129 sg:person.0732145436.56 schema:affiliation grid-institutes:grid.415877.8
130 schema:familyName Ovcharenko
131 schema:givenName V. I.
132 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732145436.56
133 rdf:type schema:Person
134 sg:person.07501453217.49 schema:affiliation grid-institutes:grid.415877.8
135 schema:familyName Fursova
136 schema:givenName E. Yu.
137 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07501453217.49
138 rdf:type schema:Person
139 grid-institutes:grid.415877.8 schema:alternateName Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk
140 schema:name Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk
141 International Tomographic Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk
142 Novosibirsk State University, Novosibirsk
143 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...