Isotopic Study of the Formation of Phenoxazine Derivatives in the Transformations of 3,5-Di-tert-Butylcatechol Adsorbed in Thin SiO2-nTiO2 Layers in the ... View Full Text


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Article Info

DATE

2002-10

AUTHORS

B. V. Vol'eva, A. I. Prokof'ev, N. L. Komissarova, I.S. Belostotskaya, T. I. Prokof'eva, V. V. Ershov

ABSTRACT

A study was carried out on the isotopic composition of the tetra-tert-butylphenoxazine derivatives formed in the heterophase transformations of 3,5-di-tert-butylcatechol adsorbed on thin SiO2 layers with microscopic traces of Ti and Mn in a nitrogen-oxygen atmosphere enriched with 15N2. The formation of isotopically-labeled tetra-tert-butylphenoxazinyl and hydroxytetra-tert-butylphenoxazinyl radicals and tetra-tert-butylphenoxazinone indicated the participation of atmospheric nitrogen in the heterophase catalytic reaction. More... »

PAGES

1276-1282

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1021797900885

DOI

http://dx.doi.org/10.1023/a:1021797900885

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005892871


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