Effects of Metastable Diffusion Short-Circuits on Surface Segregation View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-01

AUTHORS

René Le Gall, Guy Saindrenan

ABSTRACT

The role of defects introduced by both quenching and plastic deformation on the acceleration of surface segregation kinetics in the nickel-sulphur system is discussed. An estimation of the diffusion coefficient of sulphur in as-quenched single-crystal of nickel is given. Regarding cold-worked structures, the annihilation of the vacancies produces very quick segregation of sulphur atoms on the dislocation network at the beginning of the annealing treatment. However, the diffusion acceleration becomes truly significant when the pipes inside sub-grain boundaries resulting from the deformation are rearranged properly to form a percolated network. These results demonstrate that the micro-structural evolution of diffusion short circuits should be taken into account when describing complex diffusion kinetics. More... »

PAGES

59-66

Journal

TITLE

Interface Science

ISSUE

1

VOLUME

11

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1021582823297

DOI

http://dx.doi.org/10.1023/a:1021582823297

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047282740


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