Synthesis and crystal structure of the nanosized supramolecular SmIII complex with macrocyclic cavitand cucurbituril {[Sm(H2O)4]2(C36H36N24O12)3}Br6·44H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-10

AUTHORS

D. G. Samsonenko, O. A. Gerasko, J. Lipkowski, A. V. Virovets, V. P. Fedin

ABSTRACT

The supramolecular compound {[Sm(H2O)4]2(Cuc)3}Br6·44H2O (Cuc = C36H36N24O12) was synthesized. Its crystal and molecular structure was established by X-ray diffraction analysis. The binuclear complex cation {(Cuc)[Sm(H2O)4](Cuc)[Sm(H2O)4](Cuc)}6+ built from the alternating cucurbituril molecules (C36H36N24O12) and the [Sm(H2O)4]3+ aqua ions is a triple-decker nanosized (33 Å) sandwich.

PAGES

1915-1918

References to SciGraph publications

  • 1994-09. Cucurbituril: Supramolecular perspectives for an old ligand in JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1023/a:1021316921801

    DOI

    http://dx.doi.org/10.1023/a:1021316921801

    DIMENSIONS

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