Solvent Extraction of Heavy Metals with a 23-Membered Macrocyclic Ionophore Attached with BF2+-Capped Cobalt(III) Complex View Full Text


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Article Info

DATE

2002-08

AUTHORS

Halit Kantekin, Ümmühan Ocak, Yaşar Gök

ABSTRACT

A new (E, E)-dioxime cobalt(III) complex [Co(HL)2pyCl]containing four 23-membered macrocyclic ionophores has beenprepared. The cobalt(III) complex [Co(LBF2)2pyCl]bridged with BF2+ was prepared using the precursorcobalt(III) complex and boron trifluoride ethyl ethercomplex. The solvent extraction of heavy metal cationssuch as Ni2+, Cu2+, Zn2+, Hg2+ and Pb2+ by the BF2+-capped cobalt(III) complex has been investigated. The structure of the complexes is proposedaccording to elemental analyses, 1H and 13C-NMR, IRand mass spectral data. More... »

PAGES

175-178

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1021292111325

DOI

http://dx.doi.org/10.1023/a:1021292111325

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042486197


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