Iron Uniform-Size Nanoparticles Dispersed on MCM-41 Used as Hydrocarbon Synthesis Catalyst View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-03

AUTHORS

S. G. Marchetti, M. V. Cagnoli, A. M. Alvarez, J. F. Bengoa, N. G. Gallegos, A. A. Yeramián, R. C. Mercader

ABSTRACT

We have synthesized mesoporous MCM-41 and have used it as a support for iron particles to be employed as a catalyst in the Fischer–Tropsch reaction. The solids were characterized by Mössbauer spectroscopy, X-ray diffraction, BET, TGA, CO chemisorption and volumetric oxidation. Although the catalyst showed a high CO conversion when it was used in the hydrocarbon synthesis from CO and H2 (14.3% at 1 h of reaction time) mainly methane was formed. The high methane production is likely related to the very small size of the metal particles obtained. We suggest some ways to improve the selectivity. More... »

PAGES

33-40

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1021263119841

DOI

http://dx.doi.org/10.1023/a:1021263119841

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1014219007


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Centro de Investigaci\u00f3n y Desarrollo en Procesos Catal\u00edticos (CINDECA, CONICET, CIC), Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina", 
            "Departamento de Qu\u00edmica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Marchetti", 
        "givenName": "S. G.", 
        "id": "sg:person.015336512225.82", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015336512225.82"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Centro de Investigaci\u00f3n y Desarrollo en Procesos Catal\u00edticos (CINDECA, CONICET, CIC), Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina", 
            "Departamento de Qu\u00edmica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Cagnoli", 
        "givenName": "M. V.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Centro de Investigaci\u00f3n y Desarrollo en Procesos Catal\u00edticos (CINDECA, CONICET, CIC), Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina", 
            "Departamento de Qu\u00edmica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Alvarez", 
        "givenName": "A. M.", 
        "id": "sg:person.014533774514.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014533774514.15"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Centro de Investigaci\u00f3n y Desarrollo en Procesos Catal\u00edticos (CINDECA, CONICET, CIC), Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bengoa", 
        "givenName": "J. F.", 
        "id": "sg:person.011621343025.24", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011621343025.24"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Centro de Investigaci\u00f3n y Desarrollo en Procesos Catal\u00edticos (CINDECA, CONICET, CIC), Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina", 
            "Departamento de Qu\u00edmica, Facultad de Ingenier\u00eda, Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gallegos", 
        "givenName": "N. G.", 
        "id": "sg:person.015564047715.00", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015564047715.00"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National University of La Plata", 
          "id": "https://www.grid.ac/institutes/grid.9499.d", 
          "name": [
            "Centro de Investigaci\u00f3n y Desarrollo en Procesos Catal\u00edticos (CINDECA, CONICET, CIC), Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina", 
            "Departamento de Qu\u00edmica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yerami\u00e1n", 
        "givenName": "A. A.", 
        "id": "sg:person.016362241643.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016362241643.42"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Instituto de F\u00edsica La Plata", 
          "id": "https://www.grid.ac/institutes/grid.450288.3", 
          "name": [
            "Departamento de F\u00edsica, IFLP, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mercader", 
        "givenName": "R. C.", 
        "id": "sg:person.012017136243.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012017136243.52"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1006/jcat.1996.0170", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004356889"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0169-4332(00)00363-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005867601"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0169-4332(00)00364-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006626087"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0953-8984/4/31/008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009832879"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00770991", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015836623", 
          "https://doi.org/10.1007/bf00770991"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00770991", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015836623", 
          "https://doi.org/10.1007/bf00770991"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0166-9834(00)82802-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018809280"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00895017", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027372665", 
          "https://doi.org/10.1007/bf00895017"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2002-03", 
    "datePublishedReg": "2002-03-01", 
    "description": "We have synthesized mesoporous MCM-41 and have used it as a support for iron particles to be employed as a catalyst in the Fischer\u2013Tropsch reaction. The solids were characterized by M\u00f6ssbauer spectroscopy, X-ray diffraction, BET, TGA, CO chemisorption and volumetric oxidation. Although the catalyst showed a high CO conversion when it was used in the hydrocarbon synthesis from CO and H2 (14.3% at 1 h of reaction time) mainly methane was formed. The high methane production is likely related to the very small size of the metal particles obtained. We suggest some ways to improve the selectivity.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1023/a:1021263119841", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1038685", 
        "issn": [
          "0304-3843", 
          "1572-9540"
        ], 
        "name": "Hyperfine Interactions", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1-4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "139-140"
      }
    ], 
    "name": "Iron Uniform-Size Nanoparticles Dispersed on MCM-41 Used as Hydrocarbon Synthesis Catalyst", 
    "pagination": "33-40", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "43bd8dd6ebcb41ef7bc834e9883f271dfc8896251b480bbfc935dcabf9da44be"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/a:1021263119841"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1014219007"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/a:1021263119841", 
      "https://app.dimensions.ai/details/publication/pub.1014219007"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T13:13", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8659_00000504.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1023%2FA%3A1021263119841"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1021263119841'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1021263119841'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1021263119841'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1021263119841'


 

This table displays all metadata directly associated to this object as RDF triples.

130 TRIPLES      21 PREDICATES      34 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/a:1021263119841 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N76c558601c974a34a858db67c201ee40
4 schema:citation sg:pub.10.1007/bf00770991
5 sg:pub.10.1007/bf00895017
6 https://doi.org/10.1006/jcat.1996.0170
7 https://doi.org/10.1016/s0166-9834(00)82802-x
8 https://doi.org/10.1016/s0169-4332(00)00363-9
9 https://doi.org/10.1016/s0169-4332(00)00364-0
10 https://doi.org/10.1088/0953-8984/4/31/008
11 schema:datePublished 2002-03
12 schema:datePublishedReg 2002-03-01
13 schema:description We have synthesized mesoporous MCM-41 and have used it as a support for iron particles to be employed as a catalyst in the Fischer–Tropsch reaction. The solids were characterized by Mössbauer spectroscopy, X-ray diffraction, BET, TGA, CO chemisorption and volumetric oxidation. Although the catalyst showed a high CO conversion when it was used in the hydrocarbon synthesis from CO and H2 (14.3% at 1 h of reaction time) mainly methane was formed. The high methane production is likely related to the very small size of the metal particles obtained. We suggest some ways to improve the selectivity.
14 schema:genre research_article
15 schema:inLanguage en
16 schema:isAccessibleForFree false
17 schema:isPartOf N3086e1066c8847448c48023c96b383bd
18 Ncb5887969d0d4bc8a8e28c76b84eb622
19 sg:journal.1038685
20 schema:name Iron Uniform-Size Nanoparticles Dispersed on MCM-41 Used as Hydrocarbon Synthesis Catalyst
21 schema:pagination 33-40
22 schema:productId N09243c3ae8554ee5b5df5dfddb244017
23 N2e2d729653724698b3d486737965ea01
24 N659290e1c50e40219cae8e22748af335
25 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014219007
26 https://doi.org/10.1023/a:1021263119841
27 schema:sdDatePublished 2019-04-10T13:13
28 schema:sdLicense https://scigraph.springernature.com/explorer/license/
29 schema:sdPublisher N316e692e9e50447385ebec361d5fafa1
30 schema:url http://link.springer.com/10.1023%2FA%3A1021263119841
31 sgo:license sg:explorer/license/
32 sgo:sdDataset articles
33 rdf:type schema:ScholarlyArticle
34 N09243c3ae8554ee5b5df5dfddb244017 schema:name dimensions_id
35 schema:value pub.1014219007
36 rdf:type schema:PropertyValue
37 N101a3b55db0447548221b65f67cd8437 rdf:first sg:person.016362241643.42
38 rdf:rest N66193eb5f8b947a6839aea8fb6da00ac
39 N2e0aef5f96ab4a1aa5ca5587ebf218a7 rdf:first sg:person.014533774514.15
40 rdf:rest N3bffcef5fe4a46c9b2a39c5640e27aea
41 N2e2d729653724698b3d486737965ea01 schema:name doi
42 schema:value 10.1023/a:1021263119841
43 rdf:type schema:PropertyValue
44 N3086e1066c8847448c48023c96b383bd schema:issueNumber 1-4
45 rdf:type schema:PublicationIssue
46 N316e692e9e50447385ebec361d5fafa1 schema:name Springer Nature - SN SciGraph project
47 rdf:type schema:Organization
48 N3bffcef5fe4a46c9b2a39c5640e27aea rdf:first sg:person.011621343025.24
49 rdf:rest Nca799d8f0f754111bc2e4679c6b448d7
50 N659290e1c50e40219cae8e22748af335 schema:name readcube_id
51 schema:value 43bd8dd6ebcb41ef7bc834e9883f271dfc8896251b480bbfc935dcabf9da44be
52 rdf:type schema:PropertyValue
53 N66193eb5f8b947a6839aea8fb6da00ac rdf:first sg:person.012017136243.52
54 rdf:rest rdf:nil
55 N76c558601c974a34a858db67c201ee40 rdf:first sg:person.015336512225.82
56 rdf:rest N9d65537a18134ead81cb8b5bdd358fd2
57 N9c20f5cfdb504bc38eb14f71a6f68c97 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
58 schema:familyName Cagnoli
59 schema:givenName M. V.
60 rdf:type schema:Person
61 N9d65537a18134ead81cb8b5bdd358fd2 rdf:first N9c20f5cfdb504bc38eb14f71a6f68c97
62 rdf:rest N2e0aef5f96ab4a1aa5ca5587ebf218a7
63 Nca799d8f0f754111bc2e4679c6b448d7 rdf:first sg:person.015564047715.00
64 rdf:rest N101a3b55db0447548221b65f67cd8437
65 Ncb5887969d0d4bc8a8e28c76b84eb622 schema:volumeNumber 139-140
66 rdf:type schema:PublicationVolume
67 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
68 schema:name Chemical Sciences
69 rdf:type schema:DefinedTerm
70 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
71 schema:name Physical Chemistry (incl. Structural)
72 rdf:type schema:DefinedTerm
73 sg:journal.1038685 schema:issn 0304-3843
74 1572-9540
75 schema:name Hyperfine Interactions
76 rdf:type schema:Periodical
77 sg:person.011621343025.24 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
78 schema:familyName Bengoa
79 schema:givenName J. F.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011621343025.24
81 rdf:type schema:Person
82 sg:person.012017136243.52 schema:affiliation https://www.grid.ac/institutes/grid.450288.3
83 schema:familyName Mercader
84 schema:givenName R. C.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012017136243.52
86 rdf:type schema:Person
87 sg:person.014533774514.15 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
88 schema:familyName Alvarez
89 schema:givenName A. M.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014533774514.15
91 rdf:type schema:Person
92 sg:person.015336512225.82 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
93 schema:familyName Marchetti
94 schema:givenName S. G.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015336512225.82
96 rdf:type schema:Person
97 sg:person.015564047715.00 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
98 schema:familyName Gallegos
99 schema:givenName N. G.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015564047715.00
101 rdf:type schema:Person
102 sg:person.016362241643.42 schema:affiliation https://www.grid.ac/institutes/grid.9499.d
103 schema:familyName Yeramián
104 schema:givenName A. A.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016362241643.42
106 rdf:type schema:Person
107 sg:pub.10.1007/bf00770991 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015836623
108 https://doi.org/10.1007/bf00770991
109 rdf:type schema:CreativeWork
110 sg:pub.10.1007/bf00895017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027372665
111 https://doi.org/10.1007/bf00895017
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1006/jcat.1996.0170 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004356889
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1016/s0166-9834(00)82802-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1018809280
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1016/s0169-4332(00)00363-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005867601
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1016/s0169-4332(00)00364-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006626087
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1088/0953-8984/4/31/008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009832879
122 rdf:type schema:CreativeWork
123 https://www.grid.ac/institutes/grid.450288.3 schema:alternateName Instituto de Física La Plata
124 schema:name Departamento de Física, IFLP, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina
125 rdf:type schema:Organization
126 https://www.grid.ac/institutes/grid.9499.d schema:alternateName National University of La Plata
127 schema:name Centro de Investigación y Desarrollo en Procesos Catalíticos (CINDECA, CONICET, CIC), Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina
128 Departamento de Química, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina
129 Departamento de Química, Facultad de Ingeniería, Universidad Nacional de La Plata, 47 115, 1900, La Plata, Argentina
130 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...