Extraction Properties of Dibutylphosphoric Acid Zirconium Salt in Recovery of Transplutonium and Rare-Earth Elements from Nitric Acid Solution View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-09

AUTHORS

O. V. Shmidt, B. Ya. Zilberman, Yu. S. Fedorov, D. N. Suglobov, E. A. Puzikov, L. G. Mashirov, Yu. V. Palenik, R. G. Glekov

ABSTRACT

The structures of dibutylphosphoric acid zirconium salt (Zr-DBP) and of the complexes formed in the organic phase in extraction of rare-earth elements with Zr-DBP were suggested on the basis of the extraction and IR data. The influence exerted by the acidity, Zr-DBP concentraiton, and degree of extractant saturation with the metal on the structure of the complexes was examined. The contributions of various extraction mechanisms for all the rare-earth elements and also for Am and Cm were revealed by mathematical simulation. Irrespective of the diluent, addition of TBP to Zr-DBP decreases the distribution factors of Ce, Eu, and Am but increases the extractant capacity for rare-earth elements by a value that considerably exceeds the extraction of the elements with TBP taken separately. More... »

PAGES

472-477

Journal

TITLE

Radiochemistry

ISSUE

5

VOLUME

44

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1021179308191

DOI

http://dx.doi.org/10.1023/a:1021179308191

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037974179


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