UV-Induced Formation of [Fe(bpy)3]2+ Complex and its Confinement into Silica Fine Particles View Full Text


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Article Info

DATE

2003-01

AUTHORS

Chikashi Nakanishi, Saori Ikeda, Tetsuhiko Isobe, Mamoru Senna

ABSTRACT

Silica fine particles in a single or sub-micrometer regime, containing FeCl3 and 2,2′-bipyridine (bpy), were prepared by utilizing reverse micellar method. Formation of tris-bpy iron(II) ([Fe(bpy)3]2+) complex was induced in the silica fine particles by UV irradiation at 365 nm. The starting micellar solution was obtained by an injection of 0.04 cm3 HCl aqueous solution into 5 cm3 tetraethyl orthosilicate (TEOS)/cyclohexane (2 cm3/3 cm3) mixed solution containing 4–14 vol% of nonionic surfactant, polyoxyethylene(5) nonylphenyl ether (NP-5). Size of the silica particles was regulated by the concentration of NP-5. More... »

PAGES

103-106

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1020749604691

DOI

http://dx.doi.org/10.1023/a:1020749604691

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044964919


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