TTT Cure Diagram View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-08

AUTHORS

Lisardo Núñez, L. Fraga, M. R. Núñez, M. Villanueva, B. Rial

ABSTRACT

Curing reactions of the epoxy system consisting of a diglycidyl ether of bisphenol A (BADGE n=0) and m-xylylenediamine (m-XDA) were studied to calculate time-temperature-transformation (TTT) isothermal cure diagram for this system. Gel times were measured as a function of temperature using solubility test. Differential scanning calorimetry (DSC) was used to calculate the vitrification times. DSC data show a one-to-one relationship between Tg and fractional conversion, a independent of cure temperature. As a consequence, Tg can be used as a measure of conversion. The activation energy for the polymerization overall reaction was calculated from the gel times obtained using the solubility test (41.5 kJ mol-1). This value is similar to the results obtained for other similar epoxy systems. Isoconversion contours were calculated by numerical integration of the best fitting kinetic model. More... »

PAGES

9-17

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1020628911473

DOI

http://dx.doi.org/10.1023/a:1020628911473

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022830135


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