Polarized Fluorescence of Jet‐Cooled Indole View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-07

AUTHORS

N. A. Borisevich, S. L. Derzhitskii, V. A. Povedailo, V. A. Tolkachev

ABSTRACT

The polarization of indole fluorescence on excitation in the P, Q, and R branches of a purely electron transition has been investigated. Relations are given to calculate the fluorescence polarization with arbitrary orientation of the dipole moments of transitions with absorption and emission and with excitation in the Q branch of the vibronic line. The coincidence of the measured (7.3%) and calculated (7.7%) values of the polarization degree confirms the reported intramolecular orientation of the dipole moment of transition. The measured fluorescence polarization degree on nonselective excitation is about 3%. More... »

PAGES

571-574

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1020608216617

DOI

http://dx.doi.org/10.1023/a:1020608216617

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1021407334


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0502", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Environmental Science and Management", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/05", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Environmental Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Belarus", 
          "id": "https://www.grid.ac/institutes/grid.410300.6", 
          "name": [
            "Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70 F. Skorina Ave., 220072, Minsk, Belarus"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Borisevich", 
        "givenName": "N. A.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Belarus", 
          "id": "https://www.grid.ac/institutes/grid.410300.6", 
          "name": [
            "Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70 F. Skorina Ave., 220072, Minsk, Belarus"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Derzhitskii", 
        "givenName": "S. L.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Belarus", 
          "id": "https://www.grid.ac/institutes/grid.410300.6", 
          "name": [
            "Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70 F. Skorina Ave., 220072, Minsk, Belarus"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Povedailo", 
        "givenName": "V. A.", 
        "id": "sg:person.07522503641.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07522503641.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Belarus", 
          "id": "https://www.grid.ac/institutes/grid.410300.6", 
          "name": [
            "Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70 F. Skorina Ave., 220072, Minsk, Belarus"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tolkachev", 
        "givenName": "V. A.", 
        "id": "sg:person.015253632206.54", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015253632206.54"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0009-2614(87)85129-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039208833"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00387019508009891", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042367190"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.452721", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058030737"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.469974", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058047958"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2002-07", 
    "datePublishedReg": "2002-07-01", 
    "description": "The polarization of indole fluorescence on excitation in the P, Q, and R branches of a purely electron transition has been investigated. Relations are given to calculate the fluorescence polarization with arbitrary orientation of the dipole moments of transitions with absorption and emission and with excitation in the Q branch of the vibronic line. The coincidence of the measured (7.3%) and calculated (7.7%) values of the polarization degree confirms the reported intramolecular orientation of the dipole moment of transition. The measured fluorescence polarization degree on nonselective excitation is about 3%.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1023/a:1020608216617", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1005931", 
        "issn": [
          "0021-9037", 
          "1573-8647"
        ], 
        "name": "Journal of Applied Spectroscopy", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "69"
      }
    ], 
    "name": "Polarized Fluorescence of Jet\u2010Cooled Indole", 
    "pagination": "571-574", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "65fe8c4e848687d1d8c413df7d9530e356eaf11fe34aaf467ba4d2f52ae7d850"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/a:1020608216617"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1021407334"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/a:1020608216617", 
      "https://app.dimensions.ai/details/publication/pub.1021407334"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T14:07", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8660_00000505.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1023%2FA%3A1020608216617"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1020608216617'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1020608216617'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1020608216617'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1020608216617'


 

This table displays all metadata directly associated to this object as RDF triples.

92 TRIPLES      21 PREDICATES      31 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/a:1020608216617 schema:about anzsrc-for:05
2 anzsrc-for:0502
3 schema:author N1396f61426814bd3b6e310f82c3853ae
4 schema:citation https://doi.org/10.1016/0009-2614(87)85129-1
5 https://doi.org/10.1063/1.452721
6 https://doi.org/10.1063/1.469974
7 https://doi.org/10.1080/00387019508009891
8 schema:datePublished 2002-07
9 schema:datePublishedReg 2002-07-01
10 schema:description The polarization of indole fluorescence on excitation in the P, Q, and R branches of a purely electron transition has been investigated. Relations are given to calculate the fluorescence polarization with arbitrary orientation of the dipole moments of transitions with absorption and emission and with excitation in the Q branch of the vibronic line. The coincidence of the measured (7.3%) and calculated (7.7%) values of the polarization degree confirms the reported intramolecular orientation of the dipole moment of transition. The measured fluorescence polarization degree on nonselective excitation is about 3%.
11 schema:genre research_article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N0388549fd80649ad872375427f6b5197
15 Nf09511fa912f4b6582f747f9977044dc
16 sg:journal.1005931
17 schema:name Polarized Fluorescence of Jet‐Cooled Indole
18 schema:pagination 571-574
19 schema:productId N1bdc1221051d4a9c9329eb5a8f9da50d
20 Nd14d9d2b9c3c467391a3c702e39ac3b2
21 Nfeadfe8aa26f42d1984593d5da4439cf
22 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021407334
23 https://doi.org/10.1023/a:1020608216617
24 schema:sdDatePublished 2019-04-10T14:07
25 schema:sdLicense https://scigraph.springernature.com/explorer/license/
26 schema:sdPublisher N856a326506e14ae0932a024d88124f68
27 schema:url http://link.springer.com/10.1023%2FA%3A1020608216617
28 sgo:license sg:explorer/license/
29 sgo:sdDataset articles
30 rdf:type schema:ScholarlyArticle
31 N0388549fd80649ad872375427f6b5197 schema:issueNumber 4
32 rdf:type schema:PublicationIssue
33 N1396f61426814bd3b6e310f82c3853ae rdf:first Ne0bad4fe02274ce7bd1509bf8690a3ce
34 rdf:rest N45400273df3a4ef499294ab1e4fe3894
35 N1bdc1221051d4a9c9329eb5a8f9da50d schema:name readcube_id
36 schema:value 65fe8c4e848687d1d8c413df7d9530e356eaf11fe34aaf467ba4d2f52ae7d850
37 rdf:type schema:PropertyValue
38 N45400273df3a4ef499294ab1e4fe3894 rdf:first Nafbc3be24a67462e943baee4df6b543c
39 rdf:rest Nc2ffbc856a23406fa869f8e250a96167
40 N77af62f4351740759a0ed5bb0405657b rdf:first sg:person.015253632206.54
41 rdf:rest rdf:nil
42 N856a326506e14ae0932a024d88124f68 schema:name Springer Nature - SN SciGraph project
43 rdf:type schema:Organization
44 Nafbc3be24a67462e943baee4df6b543c schema:affiliation https://www.grid.ac/institutes/grid.410300.6
45 schema:familyName Derzhitskii
46 schema:givenName S. L.
47 rdf:type schema:Person
48 Nc2ffbc856a23406fa869f8e250a96167 rdf:first sg:person.07522503641.48
49 rdf:rest N77af62f4351740759a0ed5bb0405657b
50 Nd14d9d2b9c3c467391a3c702e39ac3b2 schema:name doi
51 schema:value 10.1023/a:1020608216617
52 rdf:type schema:PropertyValue
53 Ne0bad4fe02274ce7bd1509bf8690a3ce schema:affiliation https://www.grid.ac/institutes/grid.410300.6
54 schema:familyName Borisevich
55 schema:givenName N. A.
56 rdf:type schema:Person
57 Nf09511fa912f4b6582f747f9977044dc schema:volumeNumber 69
58 rdf:type schema:PublicationVolume
59 Nfeadfe8aa26f42d1984593d5da4439cf schema:name dimensions_id
60 schema:value pub.1021407334
61 rdf:type schema:PropertyValue
62 anzsrc-for:05 schema:inDefinedTermSet anzsrc-for:
63 schema:name Environmental Sciences
64 rdf:type schema:DefinedTerm
65 anzsrc-for:0502 schema:inDefinedTermSet anzsrc-for:
66 schema:name Environmental Science and Management
67 rdf:type schema:DefinedTerm
68 sg:journal.1005931 schema:issn 0021-9037
69 1573-8647
70 schema:name Journal of Applied Spectroscopy
71 rdf:type schema:Periodical
72 sg:person.015253632206.54 schema:affiliation https://www.grid.ac/institutes/grid.410300.6
73 schema:familyName Tolkachev
74 schema:givenName V. A.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015253632206.54
76 rdf:type schema:Person
77 sg:person.07522503641.48 schema:affiliation https://www.grid.ac/institutes/grid.410300.6
78 schema:familyName Povedailo
79 schema:givenName V. A.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07522503641.48
81 rdf:type schema:Person
82 https://doi.org/10.1016/0009-2614(87)85129-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039208833
83 rdf:type schema:CreativeWork
84 https://doi.org/10.1063/1.452721 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058030737
85 rdf:type schema:CreativeWork
86 https://doi.org/10.1063/1.469974 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058047958
87 rdf:type schema:CreativeWork
88 https://doi.org/10.1080/00387019508009891 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042367190
89 rdf:type schema:CreativeWork
90 https://www.grid.ac/institutes/grid.410300.6 schema:alternateName National Academy of Sciences of Belarus
91 schema:name Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70 F. Skorina Ave., 220072, Minsk, Belarus
92 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...