Radiation-Chemical Resistance of Anion Exchangers and Safety of Sorption Processes in Nitric Acid Solutions: IV. Thermal Gravimetric Study of VP-1AP ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-03

AUTHORS

S. A. Bartenev, G. M. Zachinyaev, E. R. Nazin, L. N. Lazarev, V. N. Romanovskii, S. A. Strelkov, N. G. Firsin, G. F. Egorov, L. V. Krasnikov, M. L. Hyder

ABSTRACT

Thermal gravimetric analysis of the samples of VP-1AP anion exchanger in sulfate and nitrate forms was carried out. In the derivatograms of the anion exchanger in the nitrate form there are one endothermic and two exothermic peaks (∼100, 160-180, and 200-220°C). Heating of dry samples of VP-1AP anion exchanger in the nitrate form at 130-230°C induces oxidative degradation of the sorbent matrix with participation of nitrate ions. In the presence of products of anion exchanger degradation and sorbed HNO3 in the anion exchanger phase, the weight loss of the samples abruptly increases at temperatures of approximately 180-190°C. The action of ionizing radiation strongly affects the heat resistance of the anion exchanger. At absorpbed dose of 5 MGy the first exothermic peak is shifted by 15-20°C; in this case, both exothermic peaks coalesce and the oxidation can be considered as single-stage process starting at 110°C. More... »

PAGES

162-166

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1019623313368

DOI

http://dx.doi.org/10.1023/a:1019623313368

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017486606


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0915", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Interdisciplinary Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "Khlopin Radium Institute, Research and Production Association, St. Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bartenev", 
        "givenName": "S. A.", 
        "id": "sg:person.014150257763.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014150257763.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Timoshenko Military Institute of Radiation, Chemical, and Biological Protection, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zachinyaev", 
        "givenName": "G. M.", 
        "id": "sg:person.010772414115.98", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010772414115.98"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Timoshenko Military Institute of Radiation, Chemical, and Biological Protection, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nazin", 
        "givenName": "E. R.", 
        "id": "sg:person.014742341211.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014742341211.27"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "Khlopin Radium Institute, Research and Production Association, St. Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lazarev", 
        "givenName": "L. N.", 
        "id": "sg:person.012710616171.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012710616171.75"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "Khlopin Radium Institute, Research and Production Association, St. Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Romanovskii", 
        "givenName": "V. N.", 
        "id": "sg:person.016077373400.63", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016077373400.63"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "Khlopin Radium Institute, Research and Production Association, St. Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Strelkov", 
        "givenName": "S. A.", 
        "id": "sg:person.016224175332.33", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016224175332.33"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "Khlopin Radium Institute, Research and Production Association, St. Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Firsin", 
        "givenName": "N. G.", 
        "id": "sg:person.07755525215.14", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07755525215.14"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Russian Academy of Sciences, Frumkin Institute of Electrochemistry, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Egorov", 
        "givenName": "G. F.", 
        "id": "sg:person.014075127401.67", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014075127401.67"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "Khlopin Radium Institute, Research and Production Association, St. Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Krasnikov", 
        "givenName": "L. V.", 
        "id": "sg:person.014517171243.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014517171243.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Sandia National Laboratories", 
          "id": "https://www.grid.ac/institutes/grid.474520.0", 
          "name": [
            "Sandia National Laboratory, United States"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hyder", 
        "givenName": "M. L.", 
        "id": "sg:person.016155416027.71", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016155416027.71"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2002-03", 
    "datePublishedReg": "2002-03-01", 
    "description": "Thermal gravimetric analysis of the samples of VP-1AP anion exchanger in sulfate and nitrate forms was carried out. In the derivatograms of the anion exchanger in the nitrate form there are one endothermic and two exothermic peaks (\u223c100, 160-180, and 200-220\u00b0C). Heating of dry samples of VP-1AP anion exchanger in the nitrate form at 130-230\u00b0C induces oxidative degradation of the sorbent matrix with participation of nitrate ions. In the presence of products of anion exchanger degradation and sorbed HNO3 in the anion exchanger phase, the weight loss of the samples abruptly increases at temperatures of approximately 180-190\u00b0C. The action of ionizing radiation strongly affects the heat resistance of the anion exchanger. At absorpbed dose of 5 MGy the first exothermic peak is shifted by 15-20\u00b0C; in this case, both exothermic peaks coalesce and the oxidation can be considered as single-stage process starting at 110\u00b0C.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1023/a:1019623313368", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1345524", 
        "issn": [
          "1066-3622", 
          "1608-3288"
        ], 
        "name": "Radiochemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "44"
      }
    ], 
    "name": "Radiation-Chemical Resistance of Anion Exchangers and Safety of Sorption Processes in Nitric Acid Solutions: IV. Thermal Gravimetric Study of VP-1AP Anion Exchanger in Nitrate Form", 
    "pagination": "162-166", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "53500d8c8e540e49c1d0717543851f84e24809ad9147449502eb54761366cb5a"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/a:1019623313368"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1017486606"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/a:1019623313368", 
      "https://app.dimensions.ai/details/publication/pub.1017486606"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T19:01", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8678_00000480.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1023/A:1019623313368"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1019623313368'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1019623313368'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1019623313368'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1019623313368'


 

This table displays all metadata directly associated to this object as RDF triples.

134 TRIPLES      20 PREDICATES      27 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/a:1019623313368 schema:about anzsrc-for:09
2 anzsrc-for:0915
3 schema:author N9e270839e80140e1a01d1b84546495f7
4 schema:datePublished 2002-03
5 schema:datePublishedReg 2002-03-01
6 schema:description Thermal gravimetric analysis of the samples of VP-1AP anion exchanger in sulfate and nitrate forms was carried out. In the derivatograms of the anion exchanger in the nitrate form there are one endothermic and two exothermic peaks (∼100, 160-180, and 200-220°C). Heating of dry samples of VP-1AP anion exchanger in the nitrate form at 130-230°C induces oxidative degradation of the sorbent matrix with participation of nitrate ions. In the presence of products of anion exchanger degradation and sorbed HNO3 in the anion exchanger phase, the weight loss of the samples abruptly increases at temperatures of approximately 180-190°C. The action of ionizing radiation strongly affects the heat resistance of the anion exchanger. At absorpbed dose of 5 MGy the first exothermic peak is shifted by 15-20°C; in this case, both exothermic peaks coalesce and the oxidation can be considered as single-stage process starting at 110°C.
7 schema:genre research_article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N4fff3dada2a1446caab1467acc31a9fd
11 Nd623e916528549fb81e948f0b39ce02b
12 sg:journal.1345524
13 schema:name Radiation-Chemical Resistance of Anion Exchangers and Safety of Sorption Processes in Nitric Acid Solutions: IV. Thermal Gravimetric Study of VP-1AP Anion Exchanger in Nitrate Form
14 schema:pagination 162-166
15 schema:productId N0bf2e136b6584fadb1d6b599b0b66b77
16 N387081995d4b4255be9fa19a51bf6517
17 Nd3023ad460b14f72bf02d34fcf4bc10f
18 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017486606
19 https://doi.org/10.1023/a:1019623313368
20 schema:sdDatePublished 2019-04-10T19:01
21 schema:sdLicense https://scigraph.springernature.com/explorer/license/
22 schema:sdPublisher Ne79c9d154cdc4b998972b4f8ba94808b
23 schema:url http://link.springer.com/10.1023/A:1019623313368
24 sgo:license sg:explorer/license/
25 sgo:sdDataset articles
26 rdf:type schema:ScholarlyArticle
27 N053b851f490441dc823cfa5b95798d36 rdf:first sg:person.014742341211.27
28 rdf:rest N297b96afac3848f2ab7e752b86ee29e1
29 N0bf2e136b6584fadb1d6b599b0b66b77 schema:name dimensions_id
30 schema:value pub.1017486606
31 rdf:type schema:PropertyValue
32 N1d0e0085cf8c4d8e911ead26d35c376c rdf:first sg:person.016155416027.71
33 rdf:rest rdf:nil
34 N297b96afac3848f2ab7e752b86ee29e1 rdf:first sg:person.012710616171.75
35 rdf:rest N7b5b96ba203242a1bb5e304b79cdbf02
36 N2c2b17ca48f14378adab4f5e55e2c03c rdf:first sg:person.016224175332.33
37 rdf:rest Nc393c356828e4a1eb4658ddc970b4706
38 N387081995d4b4255be9fa19a51bf6517 schema:name doi
39 schema:value 10.1023/a:1019623313368
40 rdf:type schema:PropertyValue
41 N4fff3dada2a1446caab1467acc31a9fd schema:volumeNumber 44
42 rdf:type schema:PublicationVolume
43 N57ce67ac84ce43ee9c82e36d35e20976 rdf:first sg:person.014075127401.67
44 rdf:rest N5c2bc6ee9bcd48508022e5e65fcf6196
45 N5c2bc6ee9bcd48508022e5e65fcf6196 rdf:first sg:person.014517171243.70
46 rdf:rest N1d0e0085cf8c4d8e911ead26d35c376c
47 N63b00cf98cab4bd399f8b0cae517ae50 schema:name Timoshenko Military Institute of Radiation, Chemical, and Biological Protection, Moscow, Russia
48 rdf:type schema:Organization
49 N6d0eda8602174c0ebbf1a6b7247a4319 schema:name Timoshenko Military Institute of Radiation, Chemical, and Biological Protection, Moscow, Russia
50 rdf:type schema:Organization
51 N7b5b96ba203242a1bb5e304b79cdbf02 rdf:first sg:person.016077373400.63
52 rdf:rest N2c2b17ca48f14378adab4f5e55e2c03c
53 N9e270839e80140e1a01d1b84546495f7 rdf:first sg:person.014150257763.48
54 rdf:rest Ne3088536be6e4b42a77117b28e3a8b1f
55 Nc393c356828e4a1eb4658ddc970b4706 rdf:first sg:person.07755525215.14
56 rdf:rest N57ce67ac84ce43ee9c82e36d35e20976
57 Nd3023ad460b14f72bf02d34fcf4bc10f schema:name readcube_id
58 schema:value 53500d8c8e540e49c1d0717543851f84e24809ad9147449502eb54761366cb5a
59 rdf:type schema:PropertyValue
60 Nd623e916528549fb81e948f0b39ce02b schema:issueNumber 2
61 rdf:type schema:PublicationIssue
62 Ne3088536be6e4b42a77117b28e3a8b1f rdf:first sg:person.010772414115.98
63 rdf:rest N053b851f490441dc823cfa5b95798d36
64 Ne79c9d154cdc4b998972b4f8ba94808b schema:name Springer Nature - SN SciGraph project
65 rdf:type schema:Organization
66 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
67 schema:name Engineering
68 rdf:type schema:DefinedTerm
69 anzsrc-for:0915 schema:inDefinedTermSet anzsrc-for:
70 schema:name Interdisciplinary Engineering
71 rdf:type schema:DefinedTerm
72 sg:journal.1345524 schema:issn 1066-3622
73 1608-3288
74 schema:name Radiochemistry
75 rdf:type schema:Periodical
76 sg:person.010772414115.98 schema:affiliation N6d0eda8602174c0ebbf1a6b7247a4319
77 schema:familyName Zachinyaev
78 schema:givenName G. M.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010772414115.98
80 rdf:type schema:Person
81 sg:person.012710616171.75 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
82 schema:familyName Lazarev
83 schema:givenName L. N.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012710616171.75
85 rdf:type schema:Person
86 sg:person.014075127401.67 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
87 schema:familyName Egorov
88 schema:givenName G. F.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014075127401.67
90 rdf:type schema:Person
91 sg:person.014150257763.48 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
92 schema:familyName Bartenev
93 schema:givenName S. A.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014150257763.48
95 rdf:type schema:Person
96 sg:person.014517171243.70 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
97 schema:familyName Krasnikov
98 schema:givenName L. V.
99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014517171243.70
100 rdf:type schema:Person
101 sg:person.014742341211.27 schema:affiliation N63b00cf98cab4bd399f8b0cae517ae50
102 schema:familyName Nazin
103 schema:givenName E. R.
104 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014742341211.27
105 rdf:type schema:Person
106 sg:person.016077373400.63 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
107 schema:familyName Romanovskii
108 schema:givenName V. N.
109 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016077373400.63
110 rdf:type schema:Person
111 sg:person.016155416027.71 schema:affiliation https://www.grid.ac/institutes/grid.474520.0
112 schema:familyName Hyder
113 schema:givenName M. L.
114 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016155416027.71
115 rdf:type schema:Person
116 sg:person.016224175332.33 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
117 schema:familyName Strelkov
118 schema:givenName S. A.
119 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016224175332.33
120 rdf:type schema:Person
121 sg:person.07755525215.14 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
122 schema:familyName Firsin
123 schema:givenName N. G.
124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07755525215.14
125 rdf:type schema:Person
126 https://www.grid.ac/institutes/grid.470918.3 schema:alternateName V. G. Khlopin Radium Institute
127 schema:name Khlopin Radium Institute, Research and Production Association, St. Petersburg, Russia
128 rdf:type schema:Organization
129 https://www.grid.ac/institutes/grid.474520.0 schema:alternateName Sandia National Laboratories
130 schema:name Sandia National Laboratory, United States
131 rdf:type schema:Organization
132 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
133 schema:name Russian Academy of Sciences, Frumkin Institute of Electrochemistry, Moscow, Russia
134 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...