Acylotropic Tautomerism: XXXV. RL-Inversion of Configuration of Dipolar Spyrocyclic and Open-Chain 2-Arylaminotropone Isomers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-05

AUTHORS

L. P. Olekhnovich, Z. N. Budarina, G. S. Borodkin, S. V. Kurbatov, G. S. Vaslyaeva, Yu. A. Zhdanov

ABSTRACT

RL-Inversion of chiral spirocyclic and open-chain 2-arylaminotropone derivatives with varied heteroatom (O, S, N) has been studied. Kinetic relations holding in the RL-permutation are discussed. Its mechanism includes formation and dissociation of spiro bonds and torsion stereodynamics.

PAGES

713-722

Journal

TITLE

Russian Journal of Organic Chemistry

ISSUE

5

VOLUME

38

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1019619307779

DOI

http://dx.doi.org/10.1023/a:1019619307779

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005707016


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "author": [
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Rostov State University, ul. Zorge 7, 344090, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Olekhnovich", 
        "givenName": "L. P.", 
        "id": "sg:person.015305011323.65", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015305011323.65"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Research Institute of Physical and Organic Chemistry, Rostov State University, pr. Stachki 194/3, 344104, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Budarina", 
        "givenName": "Z. N.", 
        "id": "sg:person.016677752323.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016677752323.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Research Institute of Physical and Organic Chemistry, Rostov State University, pr. Stachki 194/3, 344104, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Borodkin", 
        "givenName": "G. S.", 
        "id": "sg:person.07700033201.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07700033201.09"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Rostov State University, ul. Zorge 7, 344090, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kurbatov", 
        "givenName": "S. V.", 
        "id": "sg:person.0720366604.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0720366604.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Rostov State University, ul. Zorge 7, 344090, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vaslyaeva", 
        "givenName": "G. S.", 
        "id": "sg:person.016323254001.73", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016323254001.73"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Rostov State University, ul. Zorge 7, 344090, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhdanov", 
        "givenName": "Yu. A.", 
        "id": "sg:person.07511664165.87", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07511664165.87"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1248/cpb.13.457", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031598723"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1248/cpb.13.819", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052350287"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50101a026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055572269"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01026a081", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055762335"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2002-05", 
    "datePublishedReg": "2002-05-01", 
    "description": "RL-Inversion of chiral spirocyclic and open-chain 2-arylaminotropone derivatives with varied heteroatom (O, S, N) has been studied. Kinetic relations holding in the RL-permutation are discussed. Its mechanism includes formation and dissociation of spiro bonds and torsion stereodynamics.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1023/a:1019619307779", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136317", 
        "issn": [
          "1070-4280", 
          "1608-3393"
        ], 
        "name": "Russian Journal of Organic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "38"
      }
    ], 
    "name": "Acylotropic Tautomerism: XXXV. RL-Inversion of Configuration of Dipolar Spyrocyclic and Open-Chain 2-Arylaminotropone Isomers", 
    "pagination": "713-722", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "1b30c34042dcb4c1a94d4575f033de477216055ba319fa8700c232fc8e602621"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/a:1019619307779"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1005707016"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/a:1019619307779", 
      "https://app.dimensions.ai/details/publication/pub.1005707016"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T15:49", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000503.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1023%2FA%3A1019619307779"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1019619307779'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1019619307779'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1019619307779'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1019619307779'


 

This table displays all metadata directly associated to this object as RDF triples.

101 TRIPLES      20 PREDICATES      29 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/a:1019619307779 schema:author N52aee6d81f914c84a2458ab4a60007a9
2 schema:citation https://doi.org/10.1021/ic50101a026
3 https://doi.org/10.1021/ja01026a081
4 https://doi.org/10.1248/cpb.13.457
5 https://doi.org/10.1248/cpb.13.819
6 schema:datePublished 2002-05
7 schema:datePublishedReg 2002-05-01
8 schema:description RL-Inversion of chiral spirocyclic and open-chain 2-arylaminotropone derivatives with varied heteroatom (O, S, N) has been studied. Kinetic relations holding in the RL-permutation are discussed. Its mechanism includes formation and dissociation of spiro bonds and torsion stereodynamics.
9 schema:genre research_article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N39e9b6dd9dee46b092f3ab89bc0ccb25
13 N45fdbbf29eb2481faccf703184bc9826
14 sg:journal.1136317
15 schema:name Acylotropic Tautomerism: XXXV. RL-Inversion of Configuration of Dipolar Spyrocyclic and Open-Chain 2-Arylaminotropone Isomers
16 schema:pagination 713-722
17 schema:productId N29c6fca272cb4484bdcf72df4d699b40
18 N2f2c2bd95248485ea2f0a470c9424b69
19 N4711c901981b432f86cd672614f5360e
20 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005707016
21 https://doi.org/10.1023/a:1019619307779
22 schema:sdDatePublished 2019-04-10T15:49
23 schema:sdLicense https://scigraph.springernature.com/explorer/license/
24 schema:sdPublisher Nc199de90d8af48f7bc9d0b5a9610a2c2
25 schema:url http://link.springer.com/10.1023%2FA%3A1019619307779
26 sgo:license sg:explorer/license/
27 sgo:sdDataset articles
28 rdf:type schema:ScholarlyArticle
29 N0668bdaa46c44c1298c8488f4070ab0f rdf:first sg:person.07511664165.87
30 rdf:rest rdf:nil
31 N29c6fca272cb4484bdcf72df4d699b40 schema:name readcube_id
32 schema:value 1b30c34042dcb4c1a94d4575f033de477216055ba319fa8700c232fc8e602621
33 rdf:type schema:PropertyValue
34 N2f2c2bd95248485ea2f0a470c9424b69 schema:name dimensions_id
35 schema:value pub.1005707016
36 rdf:type schema:PropertyValue
37 N39e9b6dd9dee46b092f3ab89bc0ccb25 schema:volumeNumber 38
38 rdf:type schema:PublicationVolume
39 N3fcd8cc4c98545918bcb07faa4c64bbe rdf:first sg:person.0720366604.45
40 rdf:rest N87ac3b72dcfc4549b8b4ef42956703c2
41 N45fdbbf29eb2481faccf703184bc9826 schema:issueNumber 5
42 rdf:type schema:PublicationIssue
43 N4711c901981b432f86cd672614f5360e schema:name doi
44 schema:value 10.1023/a:1019619307779
45 rdf:type schema:PropertyValue
46 N52aee6d81f914c84a2458ab4a60007a9 rdf:first sg:person.015305011323.65
47 rdf:rest N5af03e3d6406411a904175d464537c86
48 N5af03e3d6406411a904175d464537c86 rdf:first sg:person.016677752323.96
49 rdf:rest N7ca70c327f064c2cb5df7b0400e778cd
50 N7ca70c327f064c2cb5df7b0400e778cd rdf:first sg:person.07700033201.09
51 rdf:rest N3fcd8cc4c98545918bcb07faa4c64bbe
52 N87ac3b72dcfc4549b8b4ef42956703c2 rdf:first sg:person.016323254001.73
53 rdf:rest N0668bdaa46c44c1298c8488f4070ab0f
54 Nc199de90d8af48f7bc9d0b5a9610a2c2 schema:name Springer Nature - SN SciGraph project
55 rdf:type schema:Organization
56 sg:journal.1136317 schema:issn 1070-4280
57 1608-3393
58 schema:name Russian Journal of Organic Chemistry
59 rdf:type schema:Periodical
60 sg:person.015305011323.65 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
61 schema:familyName Olekhnovich
62 schema:givenName L. P.
63 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015305011323.65
64 rdf:type schema:Person
65 sg:person.016323254001.73 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
66 schema:familyName Vaslyaeva
67 schema:givenName G. S.
68 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016323254001.73
69 rdf:type schema:Person
70 sg:person.016677752323.96 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
71 schema:familyName Budarina
72 schema:givenName Z. N.
73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016677752323.96
74 rdf:type schema:Person
75 sg:person.0720366604.45 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
76 schema:familyName Kurbatov
77 schema:givenName S. V.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0720366604.45
79 rdf:type schema:Person
80 sg:person.07511664165.87 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
81 schema:familyName Zhdanov
82 schema:givenName Yu. A.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07511664165.87
84 rdf:type schema:Person
85 sg:person.07700033201.09 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
86 schema:familyName Borodkin
87 schema:givenName G. S.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07700033201.09
89 rdf:type schema:Person
90 https://doi.org/10.1021/ic50101a026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055572269
91 rdf:type schema:CreativeWork
92 https://doi.org/10.1021/ja01026a081 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055762335
93 rdf:type schema:CreativeWork
94 https://doi.org/10.1248/cpb.13.457 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031598723
95 rdf:type schema:CreativeWork
96 https://doi.org/10.1248/cpb.13.819 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052350287
97 rdf:type schema:CreativeWork
98 https://www.grid.ac/institutes/grid.182798.d schema:alternateName Southern Federal University
99 schema:name Research Institute of Physical and Organic Chemistry, Rostov State University, pr. Stachki 194/3, 344104, Rostov-on-Don, Russia
100 Rostov State University, ul. Zorge 7, 344090, Rostov-on-Don, Russia
101 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...