Acylotropic Tautomerism: XXXV. RL-Inversion of Configuration of Dipolar Spyrocyclic and Open-Chain 2-Arylaminotropone Isomers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-05

AUTHORS

L. P. Olekhnovich, Z. N. Budarina, G. S. Borodkin, S. V. Kurbatov, G. S. Vaslyaeva, Yu. A. Zhdanov

ABSTRACT

RL-Inversion of chiral spirocyclic and open-chain 2-arylaminotropone derivatives with varied heteroatom (O, S, N) has been studied. Kinetic relations holding in the RL-permutation are discussed. Its mechanism includes formation and dissociation of spiro bonds and torsion stereodynamics.

PAGES

713-722

Journal

TITLE

Russian Journal of Organic Chemistry

ISSUE

5

VOLUME

38

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1019619307779

DOI

http://dx.doi.org/10.1023/a:1019619307779

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005707016


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