A kinetic study of methanol decomposition catalyzed over plate-type palladium catalyst View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-12

AUTHORS

Shinji Shiizaki, Ikuo Nagashima, Yasuyuki Matsumura, Masatake Haruta

ABSTRACT

A kinetic study of the catalytic methanol decomposition to carbon monoxide and hydrogen has been carried out in the pressure range of methanol up to 8 atm at 200 and 250°C over a palladium catalyst supported on an oxidized aluminum plate. The reaction pathway can be proposed as (i) dissociative adsorption of methanol to methoxyl groups and hydrogen adsorbed on palladium sites, (ii) decomposition of the methoxyl groups to carbon monoxide and hydrogen adsorbed, and (iii) desorption of the surface carbon monoxide and hydrogen species. It is suggested that the second step is rate-determining and the surface hydrogen species enhance the decomposition of the methoxyl groups. More... »

PAGES

227-230

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1019077616888

DOI

http://dx.doi.org/10.1023/a:1019077616888

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003201165


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