Double organic modification by 3‐chloropropyl and methyl groups on pure silica MCM‐41 and Ti‐MCM‐41: efficient catalyst for epoxidation of cyclododecene View Full Text


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Article Info

DATE

2000-06

AUTHORS

Asim Bhaumik, Takashi Tatsumi

ABSTRACT

Simultaneous surface modification by 3‐chloropropyl and methyl groups on the same Si atoms resulted in hydrophobic and highly ordered mesoporous silica with a very high surface area. 13C and 29Si MAS NMR spectra indicate homogeneous grafting of chloropropyl and methyl groups in the silica matrix and this organically modified Ti‐MCM‐41 shows outstanding catalytic performance in the epoxidation of cyclododecene using tert‐butyl hydroperoxide as oxidant. More... »

PAGES

181-184

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1019068127502

DOI

http://dx.doi.org/10.1023/a:1019068127502

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1008726598


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