Additive telluromolybdates. Structure and catalysis in oxidation View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1999-03

AUTHORS

Hiromu Hayashi

ABSTRACT

Additive telluromolybdates, MoO3·2TeO2 and MIIO·TeO2·MoO3 (MIITeMoO6; MII = Co, Mn, Zn), converted ethyl lactate selectively to pyruvate in a vapor‐phase fixed‐bed flow system at 250–300 °C. A synergy in activity was observed for binary TeO2–MoO3, and crystalline α‐Te2MoO7 was suggested as the active species. The Rietveld analysis of powder XRD patterns of ternary CoTeMoO6 revealed the layer structure quite different from that of the reference α‐Te2MoO7, but tellurium was again located adjacent to molybdenum linked through lattice oxygen. More... »

PAGES

43-52

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1019055214608

DOI

http://dx.doi.org/10.1023/a:1019055214608

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022618108


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