Conversion process of chlorine containing polysilanes into silicon carbide: Part I Synthesis and crosslinking of poly(chloromethyl)silanes–carbosilanes and their transformation into ... View Full Text


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Article Info

DATE

1997-03-01

AUTHORS

H.-P MARTIN, E MULLER, R RICHTER, G ROEWER, E BRENDLER

ABSTRACT

Synthesis of chlorine containing polysilanes by catalytic redistribution is described and the obtained polymers are characterized by infrared (IR)-, magic angle spinning nuclear magnetic resonance (MAS-NMR)-spectroscopy and elemental analysis. The pyrolysis of such polysilanes was investigated by thermoanalysis, IR-, MAS NMR- and electron spin resonance (ESR)-spectroscopy. The conversion process from polysilane into polycarbosilane is described in terms of the results of the performed investigations and a model of the process is developed. Differences between this conversion process and those for chlorine free polysilanes or polycarbosilanes previously described by other authors are discussed. More... »

PAGES

1381-1387

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1018577111536

DOI

http://dx.doi.org/10.1023/a:1018577111536

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002079763


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