Photolysis of Phenol and para-Chlorophenol by UV Laser Excitation View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-07

AUTHORS

V. A. Svetlichnyi, O. N. Chaikovskaya, O. K. Bazyl', R. T. Kuznetsova, I. V. Sokolova, T. N. Kopylova, Yu. P. Meshalkin

ABSTRACT

The photolysis of phenol and para-chlorophenol by irradiation with the fourth harmonic of a neodymium laser was examined using electronic absorption spectroscopy, fluorescence, and quantum-chemical techniques. It was found that the introduction of a chlorine atom into the phenol molecule increases the efficiency of photolysis of para-chlorophenol by excitation in the long-wavelength absorption band. The O–H and C–Cl bonds in the test compounds are ruptured via a predissociation mechanism in triplet states localized at the breaking bonds. More... »

PAGES

258-264

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1017688629024

DOI

http://dx.doi.org/10.1023/a:1017688629024

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009887293


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