Synthesis of 4-Benzylsulfonyl-5-polyfluoroalkyl-ν-triazoles from 1,1-Dihydropolyfluoroalkyl Benzyl Sulfones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-04

AUTHORS

V. M. Timoshenko, Ya. V. Nikolin, A. N. Chernega, E. B. Rusanov, Yu. G. Shermolovich

ABSTRACT

The reaction of 1,1-dihydropolyfluoroalkyl benzyl sulfones with sodium azide or trimethylsilyl azide in the presence of tertiary amines gives ammonium salts of 4-benzylsulfonyl-5-polyfluoroalkyl-ν-triazoles. The proposed reaction scheme includes the participation of catalytic amounts of azide ion in the cyclization of the formed intermediate vinyl azides to triazoles. X-ray analysis of 1,4-diazabicyclo[2.2.2]octane salt of 4-benzylsulfonyl-5-(ω-H-hexafluoropropyl)-ν-triazole has been carried out. More... »

PAGES

470-476

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1017604021697

DOI

http://dx.doi.org/10.1023/a:1017604021697

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003951475


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