Tin–cobalt electrodeposition from sulfate–gluconate baths View Full Text


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Article Info

DATE

2001-03

AUTHORS

E. Gómez, E. Guaus, J. Torrent, X. Alcobe, E. Vallés

ABSTRACT

The electrodeposition of tin + cobalt alloys from a slightly acidic sulfate–gluconate bath on both vitreous carbon and copper substrates has been studied for different [Sn(II)]/[Co(II)] ratios in the bath, varying between 1/10 and 1/2. A relationship between the electrochemical stripping analysis and the morphology of the deposits has been found. Two different types of deposit were obtained. At low [Sn(II)]/[Co(II)] ratios and relatively high deposition rates a nodular, cobalt-rich, nanocrystalline coating was obtained, while at high [Sn(II)]/[Co(II)] ratios and low deposition rates a new, well-defined tetragonal SnCo phase was obtained, with cell parameters of a = 3.087 Å and c = 5.849 Å. This structure favours hydrogen evolution. More... »

PAGES

349-354

References to SciGraph publications

  • 1996-04. Electrodeposition of Sn-Co alloys from gluconate baths in JOURNAL OF APPLIED ELECTROCHEMISTRY
  • 1998-01. Electrodeposition of Co–Ni alloys in JOURNAL OF APPLIED ELECTROCHEMISTRY
  • 1988-07. Characterization of electrochemically formed thin layers of binary alloys by linear sweep voltammetry in JOURNAL OF APPLIED ELECTROCHEMISTRY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1023/a:1017540305439

    DOI

    http://dx.doi.org/10.1023/a:1017540305439

    DIMENSIONS

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