PAC study on the thermal evolution of the 60ZrF4–40BaF2 glass View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1999-09

AUTHORS

M.A. Taylor, J.A. Martínez, A.R. López García, M. Dejneka

ABSTRACT

By using 181Ta probes, the PAC technique has been used to investigates the behaviour of the hyperfine interaction in 60ZrF4–40BaF2 glass from room temperature (RT) up to the glass temperature Tg (562 K). A first serie of measurements was obtained while heating the as-prepared sample from RT to Tg. A second serie was performed on the as-treated sample after cooling it down to RT and again heated to Tg. In both series the same three components of the quadrupole interaction were observed. Dynamical effects were detected in the main component and activation energies of 0.181 eV and 0.213 eV were obtained. The results are interpreted as dynamical effects associated to the movement in the fluorine ions during polyhedra rearrangements. More... »

PAGES

525-528

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1017078329726

DOI

http://dx.doi.org/10.1023/a:1017078329726

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1011574473


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