PAC study of CdFe2O4 and ZnFe2O4 View Full Text


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Article Info

DATE

1999-09

AUTHORS

A.F. Pasquevich, J. Shitu

ABSTRACT

The time-differential perturbed angular correlation technique has been used to study the temperature dependence of the electric-field gradient at 111Cd nuclei in the spinels CdFe2O4 and ZnFe2O4. The samples were doped with radioactive 111In tracers which decay to 111Cd by electron capture. For both compounds the results of the measurements show the presence of two electric quadrupole interactions. One is well defined and corresponds to a fairly symmetrical electric field gradient. The other is broadly distributed and corresponds to electric field gradients with lower symmetry. The fractions of probes associated with these interactions are temperature dependent. The interactions are analysed taking into account the possible sites in the spinel structure for In occupation. The results are compared with those obtained with other spinels. The electric field gradient associated with the octahedral site is compared with the predictions of point charge model and with Mössbauer spectroscopy results at iron site. More... »

PAGES

463-468

Journal

TITLE

Hyperfine Interactions

ISSUE

1-8

VOLUME

120-121

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1017005708345

DOI

http://dx.doi.org/10.1023/a:1017005708345

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030962649


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