Ontology type: schema:ScholarlyArticle
2001-09
AUTHORSN. Matthess, D. Schweich, B. Martin, F. Castagna
ABSTRACTA new approach for obtaining reliable kinetic data from light-off curves is proposed. By fitting laboratory and simulated light-off curves with a simple 1-D model, apparent activation energies and frequency factors are adjusted using the Simplex method. The originality of the method is that kinetic parameters are obtained sequentially using simple mixtures. The whole set of parameters is then checked against experimental results involving all the reactants. Simulation results are satisfactory despite the empirical nature of the rate laws. More... »
PAGES119-124
http://scigraph.springernature.com/pub.10.1023/a:1016695101135
DOIhttp://dx.doi.org/10.1023/a:1016695101135
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1050649914
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/1402",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Applied Economics",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/14",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Economics",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "French Institute of Petroleum",
"id": "https://www.grid.ac/institutes/grid.13464.34",
"name": [
"Institut Fran\u00e7ais du P\u00e9trole, 1-4, avenue de Bois-Pr\u00e9au, BP 311, 92506, Rueil-Malmaison Cedex, France"
],
"type": "Organization"
},
"familyName": "Matthess",
"givenName": "N.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Laboratoire de G\u00e9nie des Proc\u00e9d\u00e9s Catalytiques",
"id": "https://www.grid.ac/institutes/grid.463949.5",
"name": [
"Laboratoire du G\u00e9nie des Proc\u00e9d\u00e9s Catalytiques, CNRS-CPE, 43, boulevard du 11 Novembre 1918, BP 2077, 69616, Villeurbanne Cedex, France"
],
"type": "Organization"
},
"familyName": "Schweich",
"givenName": "D.",
"id": "sg:person.01302567061.23",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01302567061.23"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "French Institute of Petroleum",
"id": "https://www.grid.ac/institutes/grid.13464.34",
"name": [
"Institut Fran\u00e7ais du P\u00e9trole, 1-4, avenue de Bois-Pr\u00e9au, BP 311, 92506, Rueil-Malmaison Cedex, France"
],
"type": "Organization"
},
"familyName": "Martin",
"givenName": "B.",
"id": "sg:person.016330645422.33",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016330645422.33"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "French Institute of Petroleum",
"id": "https://www.grid.ac/institutes/grid.13464.34",
"name": [
"Institut Fran\u00e7ais du P\u00e9trole, 1-4, avenue de Bois-Pr\u00e9au, BP 311, 92506, Rueil-Malmaison Cedex, France"
],
"type": "Organization"
},
"familyName": "Castagna",
"givenName": "F.",
"id": "sg:person.016157441603.02",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016157441603.02"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1016/0009-2509(96)00018-8",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1032821188"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/i300005a006",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055529000"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/i300020a005",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055529520"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/i360048a006",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055530602"
],
"type": "CreativeWork"
}
],
"datePublished": "2001-09",
"datePublishedReg": "2001-09-01",
"description": "A new approach for obtaining reliable kinetic data from light-off curves is proposed. By fitting laboratory and simulated light-off curves with a simple 1-D model, apparent activation energies and frequency factors are adjusted using the Simplex method. The originality of the method is that kinetic parameters are obtained sequentially using simple mixtures. The whole set of parameters is then checked against experimental results involving all the reactants. Simulation results are satisfactory despite the empirical nature of the rate laws.",
"genre": "research_article",
"id": "sg:pub.10.1023/a:1016695101135",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1284428",
"issn": [
"1022-5528",
"1572-9028"
],
"name": "Topics in Catalysis",
"type": "Periodical"
},
{
"issueNumber": "1-4",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "16-17"
}
],
"name": "From Light-Off Curves to Kinetic Rate Expressions for Three-Way Catalysts",
"pagination": "119-124",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"f1474297c9f92efc7d0e99ea0cefd1027769294a638cf16e6b05ef54570abdab"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1023/a:1016695101135"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1050649914"
]
}
],
"sameAs": [
"https://doi.org/10.1023/a:1016695101135",
"https://app.dimensions.ai/details/publication/pub.1050649914"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T20:46",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8684_00000508.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1023/A:1016695101135"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1016695101135'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1016695101135'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1016695101135'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1016695101135'
This table displays all metadata directly associated to this object as RDF triples.
96 TRIPLES
21 PREDICATES
31 URIs
19 LITERALS
7 BLANK NODES