From Light-Off Curves to Kinetic Rate Expressions for Three-Way Catalysts View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-09

AUTHORS

N. Matthess, D. Schweich, B. Martin, F. Castagna

ABSTRACT

A new approach for obtaining reliable kinetic data from light-off curves is proposed. By fitting laboratory and simulated light-off curves with a simple 1-D model, apparent activation energies and frequency factors are adjusted using the Simplex method. The originality of the method is that kinetic parameters are obtained sequentially using simple mixtures. The whole set of parameters is then checked against experimental results involving all the reactants. Simulation results are satisfactory despite the empirical nature of the rate laws. More... »

PAGES

119-124

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1016695101135

DOI

http://dx.doi.org/10.1023/a:1016695101135

DIMENSIONS

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