Enhancement of the activities with feedstream doping by tetrachloromethane in the oxidative dehydrogenation of propane on α-magnesium pyrovanadate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-05

AUTHORS

Shigeru Sugiyama, Yutaka Iizuka, Nobuyuki Fukuda, Hiromu Hayashi

ABSTRACT

The oxidative dehydrogenation of propane to propylene has been investigated on α-magnesium pyrovanadate (Mg2V2O7) at 723 K in the presence and absence of tetrachloromethane (TCM). Under the present conditions, the conversion of propane and the selectivity to propylene were 5.0 and 74.5%, respectively, in the absence of TCM while those were 14.0 and 70.2%, respectively, upon addition of a small amount of TCM (P(TCM) = 0.34 kPa) into the feedstream on the catalyst. The conversion of propane on Mg2V2O7 without oxidant in the presence and absence of TCM revealed that a contribution of lattice oxygen in the catalyst to the oxidation was strongly controlled by the addition of TCM, resulting in the enhancement of the activity with TCM. More... »

PAGES

137-140

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1016633506257

DOI

http://dx.doi.org/10.1023/a:1016633506257

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025670331


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