Ontology type: schema:ScholarlyArticle
2002-05
AUTHORSG. A. Zenkovets, G. N. Kryukova, S. V. Tsybulya, V. F. Anufrienko, T. V. Larina, E. B. Burgina
ABSTRACTThe structure of the multicomponent catalyst Ga1Ni1P2W0.5Sb6Ox /SiO2 and its catalytic properties in propane ammoxidation are studied. The catalyst is nanostructured and consists of noncoherently spliced blocks of a multiply promoted phase with a structure of gallium antimonate, which covers SiO2 particles with a thin layer. In the multiply promoted compound with a structure of gallium antimonate, Ni2+ ions partially substitute for Ga3+ and W6+ ions partially substitute for Sb5+. This leads to an increase in the crystalline lattice parameters a and c. Phosphate ions are stabilized in the region of block interfaces. The catalyst is characterized by high efficiency in propane ammoxidation. More... »
PAGES384-390
http://scigraph.springernature.com/pub.10.1023/a:1016014103259
DOIhttp://dx.doi.org/10.1023/a:1016014103259
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