X-ray diffraction structure of Re2(CO)8[(Z)-Ph2PCH=CHPPh2]. Proof for diphosphine ligation across the Re–Re bond View Full Text


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Article Info

DATE

2001-12

AUTHORS

Simon G. Bott, Kaiyuan Yang, Michael G. Richmond

ABSTRACT

Treatment of either Re2(CO)8(μ-H)(μ-η1,η2-CH=CHBu) or Re2(CO)8(MeCN)2 with the unsaturated diphosphine ligand (Z)-Ph2PCH=CHPPh2 gives the known bridging phosphine compound Re2(CO)8[(Z)-Ph2PCH=CHPPh2]. The solid-state structure of Re2(CO)8[(Z)-Ph2PCH=CHPPh2] was established by X-ray diffraction analysis, which confirmed the attachment of the diphosphine ligand to each rhenium center. Re2(CO)8[(Z)-Ph2PCH=CHPPh2] crystallizes in the tetragonal space group P42bc, a = 18.054(2) Å, c = 22.289(4) Å, V = 7265(2) Å3, Z = 8, and dcalc = 1.900. The two Re(CO)4 units that are tethered by the diphosphine ligand exhibit a staggered rotational geometry. More... »

PAGES

485-489

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1015663115531

DOI

http://dx.doi.org/10.1023/a:1015663115531

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003623035


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