Hydrogenation on Granular Palladium-containing Catalysts: I. Hydrogenation of Tertiary Acetylene Alcohols View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-02

AUTHORS

L. N. Tolkacheva, V. P. Kislyi, S. Z. Taits, V. V. Semenov

ABSTRACT

Commercial granular palladium catalyst (0.5% of Pd on γ-Al2O3) was modified by treating with zinc acetate (type 1) or successively with zinc acetate and ammonia (type 2). The treatment significantly increased the hydrogenation selectivity for a triple bond into a double bond: to 85.3-93.1% with the type 1 catalyst and to 96.3-97.8% with the type 2 catalyst. A construction of an autoclave with a fixed bed of the granular catalyst is described. More... »

PAGES

150-152

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1015536927055

DOI

http://dx.doi.org/10.1023/a:1015536927055

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1008771970


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