Synthesis of Pseudoionones by Acid and Base Solid Catalysts View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-04

AUTHORS

M.J. Climent, A. Corma, S. Iborra, A. Velty

ABSTRACT

The preparation of pseudoionones by aldol condensation reaction between citral and acetone have been carried out in the presence of acid (HY and beta zeolites), an acid–base (amorphous aluminophosphate) and basic catalysts such as an aluminophosphate oxynitride, MgO and different activated hydrotalcites. The results showed that acid or acid–base catalysts were not successful for performing in one pot the preparation of ionones. MgO and calcined hydrotalcites showed excellent activity and selectivity to pseudoionones, with calcined hydrotalcite more selective than MgO. Moreover, the rate of reaction can be improved by activating the hydrotalcite through rehydration. This activation can be successfully done by simply adding the optimum amount of water to the calcined hydrotalcite before reaction. The inhibiting effect of the concentration citral on the catalytic activity of rehydrated hydrotalcites that has been reported to occur at 273 K can be avoided by working at a reaction temperature of 333 K. More... »

PAGES

157-163

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1015364526587

DOI

http://dx.doi.org/10.1023/a:1015364526587

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1011990411


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Instituto de Tecnolog\u00eda Qu\u00edmica", 
          "id": "https://www.grid.ac/institutes/grid.466825.b", 
          "name": [
            "Instituto de Tecnolog\u00eda Qu\u00edmica, UPV-CSIC, Universidad Polit\u00e9cnica de Valencia, Avda. de los Naranjos s/n, 46022, Valencia, Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Climent", 
        "givenName": "M.J.", 
        "id": "sg:person.0731775616.04", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0731775616.04"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Instituto de Tecnolog\u00eda Qu\u00edmica", 
          "id": "https://www.grid.ac/institutes/grid.466825.b", 
          "name": [
            "Instituto de Tecnolog\u00eda Qu\u00edmica, UPV-CSIC, Universidad Polit\u00e9cnica de Valencia, Avda. de los Naranjos s/n, 46022, Valencia, Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Corma", 
        "givenName": "A.", 
        "id": "sg:person.01156700224.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01156700224.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Instituto de Tecnolog\u00eda Qu\u00edmica", 
          "id": "https://www.grid.ac/institutes/grid.466825.b", 
          "name": [
            "Instituto de Tecnolog\u00eda Qu\u00edmica, UPV-CSIC, Universidad Polit\u00e9cnica de Valencia, Avda. de los Naranjos s/n, 46022, Valencia, Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Iborra", 
        "givenName": "S.", 
        "id": "sg:person.01340204245.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01340204245.25"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Instituto de Tecnolog\u00eda Qu\u00edmica", 
          "id": "https://www.grid.ac/institutes/grid.466825.b", 
          "name": [
            "Instituto de Tecnolog\u00eda Qu\u00edmica, UPV-CSIC, Universidad Polit\u00e9cnica de Valencia, Avda. de los Naranjos s/n, 46022, Valencia, Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Velty", 
        "givenName": "A.", 
        "id": "sg:person.0614600145.97", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0614600145.97"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0166-9834(91)85109-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007186417"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jcat.1996.0340", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011299935"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/hlca.19760590642", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012024661"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jcat.1997.1878", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012451150"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9517(86)90262-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021917093"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jcat.1994.1262", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033335664"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0926-860x(97)00175-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033911769"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0920-5861(00)00346-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034647989"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0926-860x(94)80219-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044573164"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.61.1008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049042682"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jcat.1995.1008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052716961"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1590/s0104-66321998000200004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1068105694"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2002-04", 
    "datePublishedReg": "2002-04-01", 
    "description": "The preparation of pseudoionones by aldol condensation reaction between citral and acetone have been carried out in the presence of acid (HY and beta zeolites), an acid\u2013base (amorphous aluminophosphate) and basic catalysts such as an aluminophosphate oxynitride, MgO and different activated hydrotalcites. The results showed that acid or acid\u2013base catalysts were not successful for performing in one pot the preparation of ionones. MgO and calcined hydrotalcites showed excellent activity and selectivity to pseudoionones, with calcined hydrotalcite more selective than MgO. Moreover, the rate of reaction can be improved by activating the hydrotalcite through rehydration. This activation can be successfully done by simply adding the optimum amount of water to the calcined hydrotalcite before reaction. The inhibiting effect of the concentration citral on the catalytic activity of rehydrated hydrotalcites that has been reported to occur at 273 K can be avoided by working at a reaction temperature of 333 K.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1023/a:1015364526587", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1126974", 
        "issn": [
          "1011-372X", 
          "1572-879X"
        ], 
        "name": "Catalysis Letters", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1-4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "79"
      }
    ], 
    "name": "Synthesis of Pseudoionones by Acid and Base Solid Catalysts", 
    "pagination": "157-163", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "392104aa12311879d05a4a4699a3f36a07abcba87588c300c1645baef1261cc6"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/a:1015364526587"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1011990411"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/a:1015364526587", 
      "https://app.dimensions.ai/details/publication/pub.1011990411"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T14:07", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8660_00000504.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1023/A:1015364526587"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1015364526587'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1015364526587'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1015364526587'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1015364526587'


 

This table displays all metadata directly associated to this object as RDF triples.

118 TRIPLES      21 PREDICATES      39 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/a:1015364526587 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Na13e2869c6194f1cba9782e08ca92efc
4 schema:citation https://doi.org/10.1002/hlca.19760590642
5 https://doi.org/10.1006/jcat.1994.1262
6 https://doi.org/10.1006/jcat.1995.1008
7 https://doi.org/10.1006/jcat.1996.0340
8 https://doi.org/10.1006/jcat.1997.1878
9 https://doi.org/10.1016/0021-9517(86)90262-9
10 https://doi.org/10.1016/0166-9834(91)85109-9
11 https://doi.org/10.1016/0926-860x(94)80219-x
12 https://doi.org/10.1016/s0920-5861(00)00346-1
13 https://doi.org/10.1016/s0926-860x(97)00175-0
14 https://doi.org/10.1246/bcsj.61.1008
15 https://doi.org/10.1590/s0104-66321998000200004
16 schema:datePublished 2002-04
17 schema:datePublishedReg 2002-04-01
18 schema:description The preparation of pseudoionones by aldol condensation reaction between citral and acetone have been carried out in the presence of acid (HY and beta zeolites), an acid–base (amorphous aluminophosphate) and basic catalysts such as an aluminophosphate oxynitride, MgO and different activated hydrotalcites. The results showed that acid or acid–base catalysts were not successful for performing in one pot the preparation of ionones. MgO and calcined hydrotalcites showed excellent activity and selectivity to pseudoionones, with calcined hydrotalcite more selective than MgO. Moreover, the rate of reaction can be improved by activating the hydrotalcite through rehydration. This activation can be successfully done by simply adding the optimum amount of water to the calcined hydrotalcite before reaction. The inhibiting effect of the concentration citral on the catalytic activity of rehydrated hydrotalcites that has been reported to occur at 273 K can be avoided by working at a reaction temperature of 333 K.
19 schema:genre research_article
20 schema:inLanguage en
21 schema:isAccessibleForFree false
22 schema:isPartOf N0ecf857d6a0b4249a29cf84798fc73ef
23 Nbc70ed6adf294b8c94ccb0d53acc72bc
24 sg:journal.1126974
25 schema:name Synthesis of Pseudoionones by Acid and Base Solid Catalysts
26 schema:pagination 157-163
27 schema:productId N1735af739ac54d67b39a311248ef3684
28 Na5bd7f0cd2d84a7a97d01687003739fd
29 Nb032fe7b8b8a41f69d6e046b04b093a9
30 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011990411
31 https://doi.org/10.1023/a:1015364526587
32 schema:sdDatePublished 2019-04-10T14:07
33 schema:sdLicense https://scigraph.springernature.com/explorer/license/
34 schema:sdPublisher N01563a9f18b5424db61276dc6d529e1f
35 schema:url http://link.springer.com/10.1023/A:1015364526587
36 sgo:license sg:explorer/license/
37 sgo:sdDataset articles
38 rdf:type schema:ScholarlyArticle
39 N01563a9f18b5424db61276dc6d529e1f schema:name Springer Nature - SN SciGraph project
40 rdf:type schema:Organization
41 N0ecf857d6a0b4249a29cf84798fc73ef schema:volumeNumber 79
42 rdf:type schema:PublicationVolume
43 N1735af739ac54d67b39a311248ef3684 schema:name readcube_id
44 schema:value 392104aa12311879d05a4a4699a3f36a07abcba87588c300c1645baef1261cc6
45 rdf:type schema:PropertyValue
46 N71f1f92eafbd496490d256cb6ad44a99 rdf:first sg:person.01340204245.25
47 rdf:rest Nd640efe8865e4e6dae547806d4a85f29
48 N77a85de9c66544b6b7868e804a0133fe rdf:first sg:person.01156700224.55
49 rdf:rest N71f1f92eafbd496490d256cb6ad44a99
50 Na13e2869c6194f1cba9782e08ca92efc rdf:first sg:person.0731775616.04
51 rdf:rest N77a85de9c66544b6b7868e804a0133fe
52 Na5bd7f0cd2d84a7a97d01687003739fd schema:name doi
53 schema:value 10.1023/a:1015364526587
54 rdf:type schema:PropertyValue
55 Nb032fe7b8b8a41f69d6e046b04b093a9 schema:name dimensions_id
56 schema:value pub.1011990411
57 rdf:type schema:PropertyValue
58 Nbc70ed6adf294b8c94ccb0d53acc72bc schema:issueNumber 1-4
59 rdf:type schema:PublicationIssue
60 Nd640efe8865e4e6dae547806d4a85f29 rdf:first sg:person.0614600145.97
61 rdf:rest rdf:nil
62 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
63 schema:name Chemical Sciences
64 rdf:type schema:DefinedTerm
65 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
66 schema:name Physical Chemistry (incl. Structural)
67 rdf:type schema:DefinedTerm
68 sg:journal.1126974 schema:issn 1011-372X
69 1572-879X
70 schema:name Catalysis Letters
71 rdf:type schema:Periodical
72 sg:person.01156700224.55 schema:affiliation https://www.grid.ac/institutes/grid.466825.b
73 schema:familyName Corma
74 schema:givenName A.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01156700224.55
76 rdf:type schema:Person
77 sg:person.01340204245.25 schema:affiliation https://www.grid.ac/institutes/grid.466825.b
78 schema:familyName Iborra
79 schema:givenName S.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01340204245.25
81 rdf:type schema:Person
82 sg:person.0614600145.97 schema:affiliation https://www.grid.ac/institutes/grid.466825.b
83 schema:familyName Velty
84 schema:givenName A.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0614600145.97
86 rdf:type schema:Person
87 sg:person.0731775616.04 schema:affiliation https://www.grid.ac/institutes/grid.466825.b
88 schema:familyName Climent
89 schema:givenName M.J.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0731775616.04
91 rdf:type schema:Person
92 https://doi.org/10.1002/hlca.19760590642 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012024661
93 rdf:type schema:CreativeWork
94 https://doi.org/10.1006/jcat.1994.1262 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033335664
95 rdf:type schema:CreativeWork
96 https://doi.org/10.1006/jcat.1995.1008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052716961
97 rdf:type schema:CreativeWork
98 https://doi.org/10.1006/jcat.1996.0340 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011299935
99 rdf:type schema:CreativeWork
100 https://doi.org/10.1006/jcat.1997.1878 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012451150
101 rdf:type schema:CreativeWork
102 https://doi.org/10.1016/0021-9517(86)90262-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021917093
103 rdf:type schema:CreativeWork
104 https://doi.org/10.1016/0166-9834(91)85109-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007186417
105 rdf:type schema:CreativeWork
106 https://doi.org/10.1016/0926-860x(94)80219-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1044573164
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1016/s0920-5861(00)00346-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034647989
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1016/s0926-860x(97)00175-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033911769
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1246/bcsj.61.1008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049042682
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1590/s0104-66321998000200004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1068105694
115 rdf:type schema:CreativeWork
116 https://www.grid.ac/institutes/grid.466825.b schema:alternateName Instituto de Tecnología Química
117 schema:name Instituto de Tecnología Química, UPV-CSIC, Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022, Valencia, Spain
118 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...