Ontology type: schema:ScholarlyArticle
2001-06
AUTHORSMatthew D. Lowther, William F. Wacholtz, Joel T. Mague
ABSTRACTThe luminescent heteroleptic Cd(II) complex bis (μ-1,2-benzenedithiolato)-1 kS, 1:2 k2S′ 2 kS, 1:2 k2S′-bis[(1,10-phenanthroline-k2N1, N1′)cadmium], [Cd2(C6H4S2)2(C12H8N2)2], containing benzenedithiolate (bdt) and 1,10-phenanthroline (phen) has been synthesized and found to have the dinuclear formulation [Cd(bdt)(phen)]2. The complex crystallizes in the space group P21/n with a = 10.3400(4), b = 11.5110(4), c = 13.6230(5) Å, and β = 106.828(2)°. The dinuclear complex has crystallographically imposed centrosymmetry with one S atom of the bdt ligand bridging the Cd atoms in an asymmetric fashion (Cd–S = 2.5743(5) and 2.6817(5) Å) while the second S atom is bound in a terminal mode (Cd–S = 2.4955(5) Å). The mean interplanar spacing between the phen ligand and the phenyl ring of the bdt ligand is 3.291 Å while that between the phen ligands of adjacent molecules is 3.363 Å, suggesting the presence of both intra- and intermolecular π-stacking. The complex is emissive in the solid state at room temperature (λem = 569 nm) with a luminecsent lifetime of 369 ns. The unstructured emission is believed to be a ligand-to-ligand π–π* charge transfer transition. More... »
PAGES295-300
http://scigraph.springernature.com/pub.10.1023/a:1014328107252
DOIhttp://dx.doi.org/10.1023/a:1014328107252
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