Phosphonium Ylides Stabilized with Cyano Group and 5-Acylamino-4-phenyl-2-thiazolyl Residue View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-11

AUTHORS

O. B. Smolii, S. Ya. Panchishin, V. V. Pirozhenko, B. S. Drach

ABSTRACT

Available ylide reagent Ph3P = C(CN)C(S)NH2 readily enters cyclocondensation with N-(chlorophenacyl)benzamide and its analogs. By this route were prepared new stabilized phosphonium ylides containing cyano group and the corresponding 5-acylamino-4-phenyl-2-thiazolyl fragment. All these compounds even under standard conditions are dephosphorylated under the action of hydrogen chloride in acetic acid to form 5-acylamino-4-phenyl-2-cyanomethylthiazoles in high yields. Their structure was proved by spectroscopic studies and independent synthesis. More... »

PAGES

1734-1736

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1013986223340

DOI

http://dx.doi.org/10.1023/a:1013986223340

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043631192


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