Molecular Mobility and Fragility in Indomethacin: A Thermally Stimulated Depolarization Current Study View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-12

AUTHORS

Natália T. Correia, Joaquim J. Moura Ramos, Marc Descamps, George Collins

ABSTRACT

PURPOSE: To show that thermally stimulated depolarization currents (TSDC), which is a dielectric experimental technique relatively unknown in the pharmaceutical scientists community, is a powerful technique to study molecular mobility in pharmaceutical solids, below their glass transition temperature (Tg). Indomethacin (Tg = 42 degrees C) is used as a model compound. METHODS: TSDC is used to isolate the individual modes of motion present in indomethacin, in the temperature range between -165 degrees C and +60 degrees C. From the experimental output of the TSDC experiments, the kinetic parameters associated with the different relaxational modes of motion were obtained, which allowed a detailed characterization of the distribution of relaxation times of the complex relaxations observed in indomethacin. RESULTS: Two different relaxational processes were detected and characterized: the glass transition relaxation, or alpha-process, and a sub-Tg relaxation, or secondary process. The lower temperature secondary process presents a very low intensity, a very low activation energy, and a very low degree of cooperativity. The fragility index (Angell's scale) of indomethacin obtained from TSDC data is m = 64, which can be compared with other values reported in the literature and obtained from other experimental techniques. CONCLUSIONS: TSDC data indicate that indomethacin is a relatively strong glass former (fragility similar to glycerol but lower than sorbitol, trehalose, and sucrose). The high-resolution power of the TSDC technique is illustrated by the fact that it detected and characterized the secondary relaxation in indomethacin, which was not possible by other techniques. More... »

PAGES

1767-1774

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1013339017070

DOI

http://dx.doi.org/10.1023/a:1013339017070

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1001905071

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/11785699


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0299", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Physical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Calorimetry", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Chemical Phenomena", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Chemistry, Physical", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Indomethacin", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Models, Chemical", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Molecular Structure", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Temperature", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of Lisbon", 
          "id": "https://www.grid.ac/institutes/grid.9983.b", 
          "name": [
            "Centro de Qu\u00edmica-F\u00edsica Molecular, Complexo I, IST, Av. Rovisco Pais, 1049-001, Lisboa, Portugal"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Correia", 
        "givenName": "Nat\u00e1lia T.", 
        "id": "sg:person.01032403102.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01032403102.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Lisbon", 
          "id": "https://www.grid.ac/institutes/grid.9983.b", 
          "name": [
            "Centro de Qu\u00edmica-F\u00edsica Molecular, Complexo I, IST, Av. Rovisco Pais, 1049-001, Lisboa, Portugal"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Moura Ramos", 
        "givenName": "Joaquim J.", 
        "id": "sg:person.016474404207.39", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016474404207.39"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Laboratoire de Dynamique et Structure des Mat\u00e9riaux Mol\u00e9culaires, UFR Physique, B\u00e2timent P5, 59655, Villeneuve d'Ascq Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Descamps", 
        "givenName": "Marc", 
        "id": "sg:person.0600626174.23", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0600626174.23"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "TherMold Partners, L.P., 652 Glenbrook Road, 06906, Stamford, Connecticut"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Collins", 
        "givenName": "George", 
        "id": "sg:person.0731074527.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0731074527.64"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1021/js9601896", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003304858"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-3093(00)00107-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007310860"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/a605242h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012481467"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1211/0022357011775172", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020179862"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0301-0104(99)00354-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023212752"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1011960112116", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023983056", 
          "https://doi.org/10.1023/a:1011960112116"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0022-3727/28/7/029", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028316392"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1012026911459", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030747176", 
          "https://doi.org/10.1023/a:1012026911459"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0032-3861(99)00445-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033324702"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0378-5173(98)00338-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050042406"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp0044126", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056045208"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp0044126", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056045208"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp983964+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056129163"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp983964+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056129163"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1286959", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057691341"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.466117", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058044123"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.478041", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058067323"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00268979709482604", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058275900"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.6028/jres.102.013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1073601101"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2001-12", 
    "datePublishedReg": "2001-12-01", 
    "description": "PURPOSE: To show that thermally stimulated depolarization currents (TSDC), which is a dielectric experimental technique relatively unknown in the pharmaceutical scientists community, is a powerful technique to study molecular mobility in pharmaceutical solids, below their glass transition temperature (Tg). Indomethacin (Tg = 42 degrees C) is used as a model compound.\nMETHODS: TSDC is used to isolate the individual modes of motion present in indomethacin, in the temperature range between -165 degrees C and +60 degrees C. From the experimental output of the TSDC experiments, the kinetic parameters associated with the different relaxational modes of motion were obtained, which allowed a detailed characterization of the distribution of relaxation times of the complex relaxations observed in indomethacin.\nRESULTS: Two different relaxational processes were detected and characterized: the glass transition relaxation, or alpha-process, and a sub-Tg relaxation, or secondary process. The lower temperature secondary process presents a very low intensity, a very low activation energy, and a very low degree of cooperativity. The fragility index (Angell's scale) of indomethacin obtained from TSDC data is m = 64, which can be compared with other values reported in the literature and obtained from other experimental techniques.\nCONCLUSIONS: TSDC data indicate that indomethacin is a relatively strong glass former (fragility similar to glycerol but lower than sorbitol, trehalose, and sucrose). The high-resolution power of the TSDC technique is illustrated by the fact that it detected and characterized the secondary relaxation in indomethacin, which was not possible by other techniques.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1023/a:1013339017070", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1094644", 
        "issn": [
          "0724-8741", 
          "1573-904X"
        ], 
        "name": "Pharmaceutical Research", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "18"
      }
    ], 
    "name": "Molecular Mobility and Fragility in Indomethacin: A Thermally Stimulated Depolarization Current Study", 
    "pagination": "1767-1774", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "0913190b96743329dc89d7a8b0153ab46d1d389e623b6f78fa90946a3fe5f7a9"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "11785699"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "8406521"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/a:1013339017070"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1001905071"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/a:1013339017070", 
      "https://app.dimensions.ai/details/publication/pub.1001905071"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T17:28", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8672_00000498.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1023/A:1013339017070"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1013339017070'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1013339017070'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1013339017070'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1013339017070'


 

This table displays all metadata directly associated to this object as RDF triples.

175 TRIPLES      21 PREDICATES      53 URIs      28 LITERALS      16 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/a:1013339017070 schema:about N123717116dc043039844e2fdaed29b28
2 N75517833dc8947c0b76fa26b72ed3d6a
3 N833197536b4a439384a132249cd5240d
4 N93d39009dd184f8e82dacd1cc8dfc3ca
5 N9ba8912bdada454a9b012f576e2dd5b9
6 Nd8fe28adcd864298bb6d3ab05c76dea8
7 Nd9d9c2ffe6994a2cad4476aa5ebd57dc
8 anzsrc-for:02
9 anzsrc-for:0299
10 schema:author Nc97d16ab821948369066dcbebeb8d74e
11 schema:citation sg:pub.10.1023/a:1011960112116
12 sg:pub.10.1023/a:1012026911459
13 https://doi.org/10.1016/s0022-3093(00)00107-1
14 https://doi.org/10.1016/s0032-3861(99)00445-0
15 https://doi.org/10.1016/s0301-0104(99)00354-7
16 https://doi.org/10.1016/s0378-5173(98)00338-x
17 https://doi.org/10.1021/jp0044126
18 https://doi.org/10.1021/jp983964+
19 https://doi.org/10.1021/js9601896
20 https://doi.org/10.1039/a605242h
21 https://doi.org/10.1063/1.1286959
22 https://doi.org/10.1063/1.466117
23 https://doi.org/10.1063/1.478041
24 https://doi.org/10.1080/00268979709482604
25 https://doi.org/10.1088/0022-3727/28/7/029
26 https://doi.org/10.1211/0022357011775172
27 https://doi.org/10.6028/jres.102.013
28 schema:datePublished 2001-12
29 schema:datePublishedReg 2001-12-01
30 schema:description PURPOSE: To show that thermally stimulated depolarization currents (TSDC), which is a dielectric experimental technique relatively unknown in the pharmaceutical scientists community, is a powerful technique to study molecular mobility in pharmaceutical solids, below their glass transition temperature (Tg). Indomethacin (Tg = 42 degrees C) is used as a model compound. METHODS: TSDC is used to isolate the individual modes of motion present in indomethacin, in the temperature range between -165 degrees C and +60 degrees C. From the experimental output of the TSDC experiments, the kinetic parameters associated with the different relaxational modes of motion were obtained, which allowed a detailed characterization of the distribution of relaxation times of the complex relaxations observed in indomethacin. RESULTS: Two different relaxational processes were detected and characterized: the glass transition relaxation, or alpha-process, and a sub-Tg relaxation, or secondary process. The lower temperature secondary process presents a very low intensity, a very low activation energy, and a very low degree of cooperativity. The fragility index (Angell's scale) of indomethacin obtained from TSDC data is m = 64, which can be compared with other values reported in the literature and obtained from other experimental techniques. CONCLUSIONS: TSDC data indicate that indomethacin is a relatively strong glass former (fragility similar to glycerol but lower than sorbitol, trehalose, and sucrose). The high-resolution power of the TSDC technique is illustrated by the fact that it detected and characterized the secondary relaxation in indomethacin, which was not possible by other techniques.
31 schema:genre research_article
32 schema:inLanguage en
33 schema:isAccessibleForFree false
34 schema:isPartOf N683fa97f94b54576ba39be12a4f1f2a9
35 N77ba17461e27429d8724307d6b0d1dad
36 sg:journal.1094644
37 schema:name Molecular Mobility and Fragility in Indomethacin: A Thermally Stimulated Depolarization Current Study
38 schema:pagination 1767-1774
39 schema:productId N3a0b37697d4a4d41a4281fa963056e67
40 N6947d8c9f4954dcda0481f7e0894431e
41 N796a2efed49a46d7afb30beaef5d01dd
42 N9225e82a9e0b4a9a9b7c18407a8e0f97
43 Nb19cf512bd6a443082ff9aaf7c47e6b3
44 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001905071
45 https://doi.org/10.1023/a:1013339017070
46 schema:sdDatePublished 2019-04-10T17:28
47 schema:sdLicense https://scigraph.springernature.com/explorer/license/
48 schema:sdPublisher Nee579da63e2d43b3829ce54f47ed5a23
49 schema:url http://link.springer.com/10.1023/A:1013339017070
50 sgo:license sg:explorer/license/
51 sgo:sdDataset articles
52 rdf:type schema:ScholarlyArticle
53 N123717116dc043039844e2fdaed29b28 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
54 schema:name Molecular Structure
55 rdf:type schema:DefinedTerm
56 N3a0b37697d4a4d41a4281fa963056e67 schema:name pubmed_id
57 schema:value 11785699
58 rdf:type schema:PropertyValue
59 N4df52004d24549edb8761d3cab4ca0d2 schema:name TherMold Partners, L.P., 652 Glenbrook Road, 06906, Stamford, Connecticut
60 rdf:type schema:Organization
61 N683fa97f94b54576ba39be12a4f1f2a9 schema:volumeNumber 18
62 rdf:type schema:PublicationVolume
63 N6947d8c9f4954dcda0481f7e0894431e schema:name readcube_id
64 schema:value 0913190b96743329dc89d7a8b0153ab46d1d389e623b6f78fa90946a3fe5f7a9
65 rdf:type schema:PropertyValue
66 N75517833dc8947c0b76fa26b72ed3d6a schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
67 schema:name Chemical Phenomena
68 rdf:type schema:DefinedTerm
69 N77ba17461e27429d8724307d6b0d1dad schema:issueNumber 12
70 rdf:type schema:PublicationIssue
71 N796a2efed49a46d7afb30beaef5d01dd schema:name doi
72 schema:value 10.1023/a:1013339017070
73 rdf:type schema:PropertyValue
74 N833197536b4a439384a132249cd5240d schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
75 schema:name Models, Chemical
76 rdf:type schema:DefinedTerm
77 N9225e82a9e0b4a9a9b7c18407a8e0f97 schema:name dimensions_id
78 schema:value pub.1001905071
79 rdf:type schema:PropertyValue
80 N933c280cf6524e099422c1f109c51a03 rdf:first sg:person.0731074527.64
81 rdf:rest rdf:nil
82 N93d39009dd184f8e82dacd1cc8dfc3ca schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
83 schema:name Temperature
84 rdf:type schema:DefinedTerm
85 N9ba8912bdada454a9b012f576e2dd5b9 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
86 schema:name Calorimetry
87 rdf:type schema:DefinedTerm
88 Nad72fa77b3c94d8794de31acad95e398 rdf:first sg:person.016474404207.39
89 rdf:rest Nbaec01190de44555947feaf621e37be2
90 Nb19cf512bd6a443082ff9aaf7c47e6b3 schema:name nlm_unique_id
91 schema:value 8406521
92 rdf:type schema:PropertyValue
93 Nbaec01190de44555947feaf621e37be2 rdf:first sg:person.0600626174.23
94 rdf:rest N933c280cf6524e099422c1f109c51a03
95 Nc97d16ab821948369066dcbebeb8d74e rdf:first sg:person.01032403102.96
96 rdf:rest Nad72fa77b3c94d8794de31acad95e398
97 Nd8fe28adcd864298bb6d3ab05c76dea8 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
98 schema:name Chemistry, Physical
99 rdf:type schema:DefinedTerm
100 Nd9d9c2ffe6994a2cad4476aa5ebd57dc schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
101 schema:name Indomethacin
102 rdf:type schema:DefinedTerm
103 Ne8d6d38b6399425c8a077fedbeb76d57 schema:name Laboratoire de Dynamique et Structure des Matériaux Moléculaires, UFR Physique, Bâtiment P5, 59655, Villeneuve d'Ascq Cedex, France
104 rdf:type schema:Organization
105 Nee579da63e2d43b3829ce54f47ed5a23 schema:name Springer Nature - SN SciGraph project
106 rdf:type schema:Organization
107 anzsrc-for:02 schema:inDefinedTermSet anzsrc-for:
108 schema:name Physical Sciences
109 rdf:type schema:DefinedTerm
110 anzsrc-for:0299 schema:inDefinedTermSet anzsrc-for:
111 schema:name Other Physical Sciences
112 rdf:type schema:DefinedTerm
113 sg:journal.1094644 schema:issn 0724-8741
114 1573-904X
115 schema:name Pharmaceutical Research
116 rdf:type schema:Periodical
117 sg:person.01032403102.96 schema:affiliation https://www.grid.ac/institutes/grid.9983.b
118 schema:familyName Correia
119 schema:givenName Natália T.
120 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01032403102.96
121 rdf:type schema:Person
122 sg:person.016474404207.39 schema:affiliation https://www.grid.ac/institutes/grid.9983.b
123 schema:familyName Moura Ramos
124 schema:givenName Joaquim J.
125 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016474404207.39
126 rdf:type schema:Person
127 sg:person.0600626174.23 schema:affiliation Ne8d6d38b6399425c8a077fedbeb76d57
128 schema:familyName Descamps
129 schema:givenName Marc
130 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0600626174.23
131 rdf:type schema:Person
132 sg:person.0731074527.64 schema:affiliation N4df52004d24549edb8761d3cab4ca0d2
133 schema:familyName Collins
134 schema:givenName George
135 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0731074527.64
136 rdf:type schema:Person
137 sg:pub.10.1023/a:1011960112116 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023983056
138 https://doi.org/10.1023/a:1011960112116
139 rdf:type schema:CreativeWork
140 sg:pub.10.1023/a:1012026911459 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030747176
141 https://doi.org/10.1023/a:1012026911459
142 rdf:type schema:CreativeWork
143 https://doi.org/10.1016/s0022-3093(00)00107-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007310860
144 rdf:type schema:CreativeWork
145 https://doi.org/10.1016/s0032-3861(99)00445-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033324702
146 rdf:type schema:CreativeWork
147 https://doi.org/10.1016/s0301-0104(99)00354-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023212752
148 rdf:type schema:CreativeWork
149 https://doi.org/10.1016/s0378-5173(98)00338-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1050042406
150 rdf:type schema:CreativeWork
151 https://doi.org/10.1021/jp0044126 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056045208
152 rdf:type schema:CreativeWork
153 https://doi.org/10.1021/jp983964+ schema:sameAs https://app.dimensions.ai/details/publication/pub.1056129163
154 rdf:type schema:CreativeWork
155 https://doi.org/10.1021/js9601896 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003304858
156 rdf:type schema:CreativeWork
157 https://doi.org/10.1039/a605242h schema:sameAs https://app.dimensions.ai/details/publication/pub.1012481467
158 rdf:type schema:CreativeWork
159 https://doi.org/10.1063/1.1286959 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057691341
160 rdf:type schema:CreativeWork
161 https://doi.org/10.1063/1.466117 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058044123
162 rdf:type schema:CreativeWork
163 https://doi.org/10.1063/1.478041 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058067323
164 rdf:type schema:CreativeWork
165 https://doi.org/10.1080/00268979709482604 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058275900
166 rdf:type schema:CreativeWork
167 https://doi.org/10.1088/0022-3727/28/7/029 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028316392
168 rdf:type schema:CreativeWork
169 https://doi.org/10.1211/0022357011775172 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020179862
170 rdf:type schema:CreativeWork
171 https://doi.org/10.6028/jres.102.013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1073601101
172 rdf:type schema:CreativeWork
173 https://www.grid.ac/institutes/grid.9983.b schema:alternateName University of Lisbon
174 schema:name Centro de Química-Física Molecular, Complexo I, IST, Av. Rovisco Pais, 1049-001, Lisboa, Portugal
175 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...