Ontology type: schema:ScholarlyArticle
2001-08
AUTHORSMojtaba Shamsipur, Gholamreza Khayatian, Sayed Yahya Kazemi, Khodabakhsh Niknam, Hashem Sharghi
ABSTRACTA synthetic procedure has been developed for the preparation of1,4-diaza-2,3;8,9-dibenzo-7,10-dioxacyclododecane-5,12-dione. A carbon paste electrode based on the new macrocyclic diamide was constructed for Ca2+determination. The calibration graph was linear over a wide concentration range (1.3 × 10-6–3.2 × 10-3 M) with a near Nernstianslope of 32 mV decade-1. The limit of detection is 7.9 × 10-7 M (0.032 ppm).Selectivity coefficients were tabulated and the working pH range was determined. It has a fast response time of <10 s and can be used for at least 3 months without any considerable divergence in potentials. The electrode was successfully applied to the determination of Ca2+ ions in a pharmaceutical preparation. More... »
PAGES303-307
http://scigraph.springernature.com/pub.10.1023/a:1012737214492
DOIhttp://dx.doi.org/10.1023/a:1012737214492
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