Mössbauer studies of magnetite and Al-substituted maghemites View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-12

AUTHORS

G.M. da Costa, E. De Grave, R.E. Vandenberghe

ABSTRACT

This paper reviews a systematic Mössbauer study of maghemite γ-Fe2O3 and Al-substituted maghemites γ-(Fe1−yAly)2O3. Three series of samples prepared from different methods and having different morphological characteristics and aluminum contents were investigated. It was found that both the cation distribution and the solubility limit depend on the preparation method, and no general conclusion in that respect could be inferred. From the temperature dependence of the hyperfine fields the exchange integrals could be calculated, and were found as: JAB= −25 K, JAA= −18 K, and JBB= −3 K. The hyperfine fields show a crossing in the vicinity of 300 K, for both substituted and unsubstituted samples, as a result of the relatively strong A–A interaction. The Curie temperatures were found to be in the range of 948–730 K, the lower value referring to the sample containing 22 mole% Al. The influence of maghemite on the Mössbauer spectra (MS) of magnetite was explored in some detail. It was demonstrated on the basis of the MS recorded for a variety of reference mixtures, that it is not possible to resolve the ferric A-site components due to maghemite and magnetite, even with the absorber subjected to a strong external field. More... »

PAGES

207-243

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1012691209853

DOI

http://dx.doi.org/10.1023/a:1012691209853

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036269124


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Universidade Federal de Ouro Preto", 
          "id": "https://www.grid.ac/institutes/grid.411213.4", 
          "name": [
            "Departamento de Qu\u00edmica, Universidade Fed. de Ouro Preto, 35400, Ouro Preto, MG, Brazil"
          ], 
          "type": "Organization"
        }, 
        "familyName": "da Costa", 
        "givenName": "G.M.", 
        "id": "sg:person.015107471761.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015107471761.29"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Ghent University", 
          "id": "https://www.grid.ac/institutes/grid.5342.0", 
          "name": [
            "Department of Subatomic and Radiation Physics, NUMAT division, University of Gent, B-9000, Gent, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "De Grave", 
        "givenName": "E.", 
        "id": "sg:person.014440363007.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014440363007.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Ghent University", 
          "id": "https://www.grid.ac/institutes/grid.5342.0", 
          "name": [
            "Department of Subatomic and Radiation Physics, NUMAT division, University of Gent, B-9000, Gent, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vandenberghe", 
        "givenName": "R.E.", 
        "id": "sg:person.07741276525.97", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07741276525.97"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1088/0953-8984/6/16/014", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000657271"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(83)90350-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002538997"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(83)90350-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002538997"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00216606", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005264199", 
          "https://doi.org/10.1007/bf00216606"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02396098", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006526553", 
          "https://doi.org/10.1007/bf02396098"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-4596(83)80010-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006570197"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-4596(83)80010-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006570197"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(92)90329-m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006641686"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(92)90329-m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006641686"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1029/96gl01411", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009863110"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0953-8984/2/4/017", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014437971"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02063726", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016374041", 
          "https://doi.org/10.1007/bf02063726"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02063726", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016374041", 
          "https://doi.org/10.1007/bf02063726"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(83)90468-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017858330"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(83)90468-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017858330"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02395855", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018201985", 
          "https://doi.org/10.1007/bf02395855"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-4596(77)90135-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021735345"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02061502", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022376326", 
          "https://doi.org/10.1007/bf02061502"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02061502", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022376326", 
          "https://doi.org/10.1007/bf02061502"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02400440", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022983964", 
          "https://doi.org/10.1007/bf02400440"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02400440", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022983964", 
          "https://doi.org/10.1007/bf02400440"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0957-0233/1/9/019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023882545"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00895017", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027372665", 
          "https://doi.org/10.1007/bf00895017"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02064602", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028238470", 
          "https://doi.org/10.1007/bf02064602"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00543881", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029928015", 
          "https://doi.org/10.1007/bf00543881"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00543881", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029928015", 
          "https://doi.org/10.1007/bf00543881"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jssc.1994.1388", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030967946"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0038-1098(77)90067-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033455509"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0038-1098(77)90067-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033455509"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0167-2738(89)90224-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033818476"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0167-2738(89)90224-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033818476"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0031-9163(66)91069-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035150695"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0031-9163(66)91069-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035150695"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00544169", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035636653", 
          "https://doi.org/10.1007/bf00544169"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00544169", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035636653", 
          "https://doi.org/10.1007/bf00544169"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9797(80)90187-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036521869"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/181044a0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037926235", 
          "https://doi.org/10.1038/181044a0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(82)90288-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044112771"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(82)90288-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044112771"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1524/zkri.1973.137.5-6.321", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047296488"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0953-8984/6/16/013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047415921"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-8853(80)90910-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047953162"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0254-0584(92)90245-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048119423"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0254-0584(92)90245-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048119423"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00200191", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050406121", 
          "https://doi.org/10.1007/bf00200191"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00200191", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050406121", 
          "https://doi.org/10.1007/bf00200191"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1051/jphyscol:1976663", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056996408"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1051/jphysrad:01951001203018900", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057011781"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1735419", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057801454"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.27.1140", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060774851"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.27.1140", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060774851"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.67.248", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060803411"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.67.248", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060803411"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.72.3278", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060809049"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.72.3278", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060809049"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1109/20.280834", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1061110400"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1109/tmag.1987.1064751", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1061673729"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1143/jjap.30.478", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1063047410"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1180/claymin.1988.023.4.03", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1064113263"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1180/minmag.1996.060.403.03", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1064120401"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1346/ccmn.1988.0360105", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1065019471"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1346/ccmn.1988.0360105", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1065019471", 
          "https://doi.org/10.1346/ccmn.1988.0360105"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1346/ccmn.1994.0420515", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1065020084"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1346/ccmn.1994.0420515", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1065020084", 
          "https://doi.org/10.1346/ccmn.1994.0420515"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1346/ccmn.1995.0430101", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1065020102"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1346/ccmn.1995.0430101", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1065020102", 
          "https://doi.org/10.1346/ccmn.1995.0430101"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2136/sssaj1980.03615995004400010028x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1069043135"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2136/sssaj1984.03615995004800060054x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1069044536"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2136/sssaj1989.03615995005300010035x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1069045952"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2136/sssaj1991.03615995005500040040x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1069046788"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2136/sssaj1991.03615995005500040041x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1069046789"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1998-12", 
    "datePublishedReg": "1998-12-01", 
    "description": "This paper reviews a systematic M\u00f6ssbauer study of maghemite \u03b3-Fe2O3 and Al-substituted maghemites \u03b3-(Fe1\u2212yAly)2O3. Three series of samples prepared from different methods and having different morphological characteristics and aluminum contents were investigated. It was found that both the cation distribution and the solubility limit depend on the preparation method, and no general conclusion in that respect could be inferred. From the temperature dependence of the hyperfine fields the exchange integrals could be calculated, and were found as: JAB= \u221225 K, JAA= \u221218 K, and JBB= \u22123 K. The hyperfine fields show a crossing in the vicinity of 300 K, for both substituted and unsubstituted samples, as a result of the relatively strong A\u2013A interaction. The Curie temperatures were found to be in the range of 948\u2013730 K, the lower value referring to the sample containing 22 mole% Al. The influence of maghemite on the M\u00f6ssbauer spectra (MS) of magnetite was explored in some detail. It was demonstrated on the basis of the MS recorded for a variety of reference mixtures, that it is not possible to resolve the ferric A-site components due to maghemite and magnetite, even with the absorber subjected to a strong external field.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1023/a:1012691209853", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1038685", 
        "issn": [
          "0304-3843", 
          "1572-9540"
        ], 
        "name": "Hyperfine Interactions", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1-4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "117"
      }
    ], 
    "name": "M\u00f6ssbauer studies of magnetite and Al-substituted maghemites", 
    "pagination": "207-243", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "acc560fee23be16eb62590b6f35c7dd8846ec886b8c7c5b12500627a9383cfad"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/a:1012691209853"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1036269124"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/a:1012691209853", 
      "https://app.dimensions.ai/details/publication/pub.1036269124"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T13:12", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8659_00000500.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1023/A:1012691209853"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1012691209853'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1012691209853'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1012691209853'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1012691209853'


 

This table displays all metadata directly associated to this object as RDF triples.

252 TRIPLES      21 PREDICATES      80 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/a:1012691209853 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author N1f2799238fd248a7a66067591814b40c
4 schema:citation sg:pub.10.1007/bf00200191
5 sg:pub.10.1007/bf00216606
6 sg:pub.10.1007/bf00543881
7 sg:pub.10.1007/bf00544169
8 sg:pub.10.1007/bf00895017
9 sg:pub.10.1007/bf02061502
10 sg:pub.10.1007/bf02063726
11 sg:pub.10.1007/bf02064602
12 sg:pub.10.1007/bf02395855
13 sg:pub.10.1007/bf02396098
14 sg:pub.10.1007/bf02400440
15 sg:pub.10.1038/181044a0
16 sg:pub.10.1346/ccmn.1988.0360105
17 sg:pub.10.1346/ccmn.1994.0420515
18 sg:pub.10.1346/ccmn.1995.0430101
19 https://doi.org/10.1006/jssc.1994.1388
20 https://doi.org/10.1016/0021-9797(80)90187-3
21 https://doi.org/10.1016/0022-4596(77)90135-9
22 https://doi.org/10.1016/0031-9163(66)91069-9
23 https://doi.org/10.1016/0038-1098(77)90067-9
24 https://doi.org/10.1016/0167-2738(89)90224-5
25 https://doi.org/10.1016/0254-0584(92)90245-4
26 https://doi.org/10.1016/0304-8853(80)90910-5
27 https://doi.org/10.1016/0304-8853(82)90288-8
28 https://doi.org/10.1016/0304-8853(83)90350-5
29 https://doi.org/10.1016/0304-8853(83)90468-7
30 https://doi.org/10.1016/0304-8853(92)90329-m
31 https://doi.org/10.1016/s0022-4596(83)80010-3
32 https://doi.org/10.1029/96gl01411
33 https://doi.org/10.1051/jphyscol:1976663
34 https://doi.org/10.1051/jphysrad:01951001203018900
35 https://doi.org/10.1063/1.1735419
36 https://doi.org/10.1088/0953-8984/2/4/017
37 https://doi.org/10.1088/0953-8984/6/16/013
38 https://doi.org/10.1088/0953-8984/6/16/014
39 https://doi.org/10.1088/0957-0233/1/9/019
40 https://doi.org/10.1103/physrevlett.27.1140
41 https://doi.org/10.1103/physrevlett.67.248
42 https://doi.org/10.1103/physrevlett.72.3278
43 https://doi.org/10.1109/20.280834
44 https://doi.org/10.1109/tmag.1987.1064751
45 https://doi.org/10.1143/jjap.30.478
46 https://doi.org/10.1180/claymin.1988.023.4.03
47 https://doi.org/10.1180/minmag.1996.060.403.03
48 https://doi.org/10.1346/ccmn.1988.0360105
49 https://doi.org/10.1346/ccmn.1994.0420515
50 https://doi.org/10.1346/ccmn.1995.0430101
51 https://doi.org/10.1524/zkri.1973.137.5-6.321
52 https://doi.org/10.2136/sssaj1980.03615995004400010028x
53 https://doi.org/10.2136/sssaj1984.03615995004800060054x
54 https://doi.org/10.2136/sssaj1989.03615995005300010035x
55 https://doi.org/10.2136/sssaj1991.03615995005500040040x
56 https://doi.org/10.2136/sssaj1991.03615995005500040041x
57 schema:datePublished 1998-12
58 schema:datePublishedReg 1998-12-01
59 schema:description This paper reviews a systematic Mössbauer study of maghemite γ-Fe2O3 and Al-substituted maghemites γ-(Fe1−yAly)2O3. Three series of samples prepared from different methods and having different morphological characteristics and aluminum contents were investigated. It was found that both the cation distribution and the solubility limit depend on the preparation method, and no general conclusion in that respect could be inferred. From the temperature dependence of the hyperfine fields the exchange integrals could be calculated, and were found as: JAB= −25 K, JAA= −18 K, and JBB= −3 K. The hyperfine fields show a crossing in the vicinity of 300 K, for both substituted and unsubstituted samples, as a result of the relatively strong A–A interaction. The Curie temperatures were found to be in the range of 948–730 K, the lower value referring to the sample containing 22 mole% Al. The influence of maghemite on the Mössbauer spectra (MS) of magnetite was explored in some detail. It was demonstrated on the basis of the MS recorded for a variety of reference mixtures, that it is not possible to resolve the ferric A-site components due to maghemite and magnetite, even with the absorber subjected to a strong external field.
60 schema:genre research_article
61 schema:inLanguage en
62 schema:isAccessibleForFree false
63 schema:isPartOf Nb2f9f9a1425c437d968695a45f41b38a
64 Ne1c1be0beb834571a4dc12c35718e127
65 sg:journal.1038685
66 schema:name Mössbauer studies of magnetite and Al-substituted maghemites
67 schema:pagination 207-243
68 schema:productId Na78ed05cd71a41c9b1ddcca85469230c
69 Nf86b6ce4f79a4c89962841d60721bbd2
70 Nfe8725ec95bc489a901deb62896bad87
71 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036269124
72 https://doi.org/10.1023/a:1012691209853
73 schema:sdDatePublished 2019-04-10T13:12
74 schema:sdLicense https://scigraph.springernature.com/explorer/license/
75 schema:sdPublisher Nc9b668784dc2405a850dc52aba55531d
76 schema:url http://link.springer.com/10.1023/A:1012691209853
77 sgo:license sg:explorer/license/
78 sgo:sdDataset articles
79 rdf:type schema:ScholarlyArticle
80 N1f2799238fd248a7a66067591814b40c rdf:first sg:person.015107471761.29
81 rdf:rest N898041a385eb4ca59a31e9735dbebfdd
82 N898041a385eb4ca59a31e9735dbebfdd rdf:first sg:person.014440363007.52
83 rdf:rest Nb0fe75975fc34d2dbed2cb98575e9e05
84 Na78ed05cd71a41c9b1ddcca85469230c schema:name dimensions_id
85 schema:value pub.1036269124
86 rdf:type schema:PropertyValue
87 Nb0fe75975fc34d2dbed2cb98575e9e05 rdf:first sg:person.07741276525.97
88 rdf:rest rdf:nil
89 Nb2f9f9a1425c437d968695a45f41b38a schema:volumeNumber 117
90 rdf:type schema:PublicationVolume
91 Nc9b668784dc2405a850dc52aba55531d schema:name Springer Nature - SN SciGraph project
92 rdf:type schema:Organization
93 Ne1c1be0beb834571a4dc12c35718e127 schema:issueNumber 1-4
94 rdf:type schema:PublicationIssue
95 Nf86b6ce4f79a4c89962841d60721bbd2 schema:name readcube_id
96 schema:value acc560fee23be16eb62590b6f35c7dd8846ec886b8c7c5b12500627a9383cfad
97 rdf:type schema:PropertyValue
98 Nfe8725ec95bc489a901deb62896bad87 schema:name doi
99 schema:value 10.1023/a:1012691209853
100 rdf:type schema:PropertyValue
101 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
102 schema:name Chemical Sciences
103 rdf:type schema:DefinedTerm
104 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
105 schema:name Macromolecular and Materials Chemistry
106 rdf:type schema:DefinedTerm
107 sg:journal.1038685 schema:issn 0304-3843
108 1572-9540
109 schema:name Hyperfine Interactions
110 rdf:type schema:Periodical
111 sg:person.014440363007.52 schema:affiliation https://www.grid.ac/institutes/grid.5342.0
112 schema:familyName De Grave
113 schema:givenName E.
114 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014440363007.52
115 rdf:type schema:Person
116 sg:person.015107471761.29 schema:affiliation https://www.grid.ac/institutes/grid.411213.4
117 schema:familyName da Costa
118 schema:givenName G.M.
119 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015107471761.29
120 rdf:type schema:Person
121 sg:person.07741276525.97 schema:affiliation https://www.grid.ac/institutes/grid.5342.0
122 schema:familyName Vandenberghe
123 schema:givenName R.E.
124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07741276525.97
125 rdf:type schema:Person
126 sg:pub.10.1007/bf00200191 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050406121
127 https://doi.org/10.1007/bf00200191
128 rdf:type schema:CreativeWork
129 sg:pub.10.1007/bf00216606 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005264199
130 https://doi.org/10.1007/bf00216606
131 rdf:type schema:CreativeWork
132 sg:pub.10.1007/bf00543881 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029928015
133 https://doi.org/10.1007/bf00543881
134 rdf:type schema:CreativeWork
135 sg:pub.10.1007/bf00544169 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035636653
136 https://doi.org/10.1007/bf00544169
137 rdf:type schema:CreativeWork
138 sg:pub.10.1007/bf00895017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027372665
139 https://doi.org/10.1007/bf00895017
140 rdf:type schema:CreativeWork
141 sg:pub.10.1007/bf02061502 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022376326
142 https://doi.org/10.1007/bf02061502
143 rdf:type schema:CreativeWork
144 sg:pub.10.1007/bf02063726 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016374041
145 https://doi.org/10.1007/bf02063726
146 rdf:type schema:CreativeWork
147 sg:pub.10.1007/bf02064602 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028238470
148 https://doi.org/10.1007/bf02064602
149 rdf:type schema:CreativeWork
150 sg:pub.10.1007/bf02395855 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018201985
151 https://doi.org/10.1007/bf02395855
152 rdf:type schema:CreativeWork
153 sg:pub.10.1007/bf02396098 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006526553
154 https://doi.org/10.1007/bf02396098
155 rdf:type schema:CreativeWork
156 sg:pub.10.1007/bf02400440 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022983964
157 https://doi.org/10.1007/bf02400440
158 rdf:type schema:CreativeWork
159 sg:pub.10.1038/181044a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037926235
160 https://doi.org/10.1038/181044a0
161 rdf:type schema:CreativeWork
162 sg:pub.10.1346/ccmn.1988.0360105 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065019471
163 https://doi.org/10.1346/ccmn.1988.0360105
164 rdf:type schema:CreativeWork
165 sg:pub.10.1346/ccmn.1994.0420515 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065020084
166 https://doi.org/10.1346/ccmn.1994.0420515
167 rdf:type schema:CreativeWork
168 sg:pub.10.1346/ccmn.1995.0430101 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065020102
169 https://doi.org/10.1346/ccmn.1995.0430101
170 rdf:type schema:CreativeWork
171 https://doi.org/10.1006/jssc.1994.1388 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030967946
172 rdf:type schema:CreativeWork
173 https://doi.org/10.1016/0021-9797(80)90187-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036521869
174 rdf:type schema:CreativeWork
175 https://doi.org/10.1016/0022-4596(77)90135-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021735345
176 rdf:type schema:CreativeWork
177 https://doi.org/10.1016/0031-9163(66)91069-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035150695
178 rdf:type schema:CreativeWork
179 https://doi.org/10.1016/0038-1098(77)90067-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033455509
180 rdf:type schema:CreativeWork
181 https://doi.org/10.1016/0167-2738(89)90224-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033818476
182 rdf:type schema:CreativeWork
183 https://doi.org/10.1016/0254-0584(92)90245-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048119423
184 rdf:type schema:CreativeWork
185 https://doi.org/10.1016/0304-8853(80)90910-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047953162
186 rdf:type schema:CreativeWork
187 https://doi.org/10.1016/0304-8853(82)90288-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044112771
188 rdf:type schema:CreativeWork
189 https://doi.org/10.1016/0304-8853(83)90350-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002538997
190 rdf:type schema:CreativeWork
191 https://doi.org/10.1016/0304-8853(83)90468-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017858330
192 rdf:type schema:CreativeWork
193 https://doi.org/10.1016/0304-8853(92)90329-m schema:sameAs https://app.dimensions.ai/details/publication/pub.1006641686
194 rdf:type schema:CreativeWork
195 https://doi.org/10.1016/s0022-4596(83)80010-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006570197
196 rdf:type schema:CreativeWork
197 https://doi.org/10.1029/96gl01411 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009863110
198 rdf:type schema:CreativeWork
199 https://doi.org/10.1051/jphyscol:1976663 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056996408
200 rdf:type schema:CreativeWork
201 https://doi.org/10.1051/jphysrad:01951001203018900 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057011781
202 rdf:type schema:CreativeWork
203 https://doi.org/10.1063/1.1735419 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057801454
204 rdf:type schema:CreativeWork
205 https://doi.org/10.1088/0953-8984/2/4/017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014437971
206 rdf:type schema:CreativeWork
207 https://doi.org/10.1088/0953-8984/6/16/013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047415921
208 rdf:type schema:CreativeWork
209 https://doi.org/10.1088/0953-8984/6/16/014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000657271
210 rdf:type schema:CreativeWork
211 https://doi.org/10.1088/0957-0233/1/9/019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023882545
212 rdf:type schema:CreativeWork
213 https://doi.org/10.1103/physrevlett.27.1140 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060774851
214 rdf:type schema:CreativeWork
215 https://doi.org/10.1103/physrevlett.67.248 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060803411
216 rdf:type schema:CreativeWork
217 https://doi.org/10.1103/physrevlett.72.3278 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060809049
218 rdf:type schema:CreativeWork
219 https://doi.org/10.1109/20.280834 schema:sameAs https://app.dimensions.ai/details/publication/pub.1061110400
220 rdf:type schema:CreativeWork
221 https://doi.org/10.1109/tmag.1987.1064751 schema:sameAs https://app.dimensions.ai/details/publication/pub.1061673729
222 rdf:type schema:CreativeWork
223 https://doi.org/10.1143/jjap.30.478 schema:sameAs https://app.dimensions.ai/details/publication/pub.1063047410
224 rdf:type schema:CreativeWork
225 https://doi.org/10.1180/claymin.1988.023.4.03 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064113263
226 rdf:type schema:CreativeWork
227 https://doi.org/10.1180/minmag.1996.060.403.03 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064120401
228 rdf:type schema:CreativeWork
229 https://doi.org/10.1346/ccmn.1988.0360105 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065019471
230 rdf:type schema:CreativeWork
231 https://doi.org/10.1346/ccmn.1994.0420515 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065020084
232 rdf:type schema:CreativeWork
233 https://doi.org/10.1346/ccmn.1995.0430101 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065020102
234 rdf:type schema:CreativeWork
235 https://doi.org/10.1524/zkri.1973.137.5-6.321 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047296488
236 rdf:type schema:CreativeWork
237 https://doi.org/10.2136/sssaj1980.03615995004400010028x schema:sameAs https://app.dimensions.ai/details/publication/pub.1069043135
238 rdf:type schema:CreativeWork
239 https://doi.org/10.2136/sssaj1984.03615995004800060054x schema:sameAs https://app.dimensions.ai/details/publication/pub.1069044536
240 rdf:type schema:CreativeWork
241 https://doi.org/10.2136/sssaj1989.03615995005300010035x schema:sameAs https://app.dimensions.ai/details/publication/pub.1069045952
242 rdf:type schema:CreativeWork
243 https://doi.org/10.2136/sssaj1991.03615995005500040040x schema:sameAs https://app.dimensions.ai/details/publication/pub.1069046788
244 rdf:type schema:CreativeWork
245 https://doi.org/10.2136/sssaj1991.03615995005500040041x schema:sameAs https://app.dimensions.ai/details/publication/pub.1069046789
246 rdf:type schema:CreativeWork
247 https://www.grid.ac/institutes/grid.411213.4 schema:alternateName Universidade Federal de Ouro Preto
248 schema:name Departamento de Química, Universidade Fed. de Ouro Preto, 35400, Ouro Preto, MG, Brazil
249 rdf:type schema:Organization
250 https://www.grid.ac/institutes/grid.5342.0 schema:alternateName Ghent University
251 schema:name Department of Subatomic and Radiation Physics, NUMAT division, University of Gent, B-9000, Gent, Belgium
252 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...