Characterisation of soil-oxide analogs by applied-field 57Fe Mössbauer spectroscopy View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-12

AUTHORS

E. De Grave, G.M. da Costa, L.H. Bowen, C.A. Barrero, R.E. Vandenberghe

ABSTRACT

In this contribution, the effect of high external magnetic fields upon the Mössbauer spectra of aluminous α- and γ-Fe2O3, of aluminous α- and γ-FeOOH and of aluminous Fe3O4 is reviewed. It is shown that the shapes of these spectra are characteristic of these materials and also to some extent of their crystallinities and Al-for-Fe substitutions. Based upon this evaluation, the potential for application of external-field Mössbauer spectroscopy to soil-related analytical purposes is demonstrated for two soil samples. Limitations of the technique are discussed. Finally, some suggestions for further research in this field are indicated. More... »

PAGES

245-270

References to SciGraph publications

  • 1991-08. Mössbauer study of the thermal decomposition of lepidocrocite and characterization of the decomposition products in PHYSICS AND CHEMISTRY OF MINERALS
  • 1990-07. Hyperfine interactions of aluminum-substituted goethites in external magnetic fields in HYPERFINE INTERACTIONS
  • 1993-02. Temporal Stability of a Fine-Grained Magnetite in CLAYS AND CLAY MINERALS
  • 1995-04. Temperature dependence of the hyperfine parameters of maghemite and al-substituted maghemites in PHYSICS AND CHEMISTRY OF MINERALS
  • 1997-05. Mössbauer spectroscopic studies on the iron forms of deep-sea sediments in PHYSICS AND CHEMISTRY OF MINERALS
  • 1996-04. 57Fe Mössbauer Effect Study of Al-Substituted Lepidocrocites in CLAYS AND CLAY MINERALS
  • 1986-02. 57Fe Mössbauer effect study of well-crystallized goethite (α-FeOOH) in HYPERFINE INTERACTIONS
  • 1990-04. The Influence of Aluminum on Iron Oxides: XIV. Al-Substituted Magnetite Synthesized at Ambient Temperatures in CLAYS AND CLAY MINERALS
  • 1990-04. The Influence of Aluminum on Iron Oxides. XV. Al-for-Fe Substitution in Synthetic Lepidocrocite in CLAYS AND CLAY MINERALS
  • 1991-12. Magnetism in aluminous goethite in PHYSICS AND CHEMISTRY OF MINERALS
  • 1995-12. Influence of Nonstoichiometry and the Presence of Maghemite on the Mössbauer Spectrum of Magnetite in CLAYS AND CLAY MINERALS
  • 1994-12. Mössbauer studies in an external field of well-crystallized Al-maghemites made from hematite in HYPERFINE INTERACTIONS
  • 1994-12. On the methodology of the analysis of Mössbauer spectra in HYPERFINE INTERACTIONS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1023/a:1012643326691

    DOI

    http://dx.doi.org/10.1023/a:1012643326691

    DIMENSIONS

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