Mössbauer characterization of iron oxides and (oxy)hydroxides: the present state of the art View Full Text


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Article Info

DATE

2000-07

AUTHORS

R.E. Vandenberghe, C.A. Barrero, G.M. da Costa, E. Van San, E. De Grave

ABSTRACT

Mössbauer spectroscopy is a powerful direct technique for the identification and quantification of iron oxides and (oxy)hydroxides in soils and sediments. However, further characterization with respect to structural properties such as crystallinity, Al substitution, stoichiometry, water content, etc. is rather limited. With some examples of synthetic and natural goethite and hematite sample series it is illustrated that the hyperfine parameters depend on much more structural features than the Al content and crystallinity alone. Neither the Morin transition in hematite nor the Verwey transition in magnetite is directly applicable for analytical purposes in natural samples. More... »

PAGES

247-259

References to SciGraph publications

  • 1991-08. Mössbauer study of the thermal decomposition of lepidocrocite and characterization of the decomposition products in PHYSICS AND CHEMISTRY OF MINERALS
  • 1986-02. Influence of Al Substitution and Crystal Size on the Room-Temperature Mössbauer Spectrum of Hematite in CLAYS AND CLAY MINERALS
  • 1982-11. Aluminous hematite: A mössbauer study in PHYSICS AND CHEMISTRY OF MINERALS
  • 1976-09. Mössbauer studies of thermal excitations in magnetically ordered microcrystals in JOURNAL OF PHYSICS D
  • 1998-12. Interplay of surface conditions, particle size, stoichiometry, cell parameters, and magnetism in synthetic hematite-like materials in HYPERFINE INTERACTIONS
  • 1977-09. Magnetic dipolar and electric quadrupolar effects on the Mössbauer spectra of magnetite above the Verwey transition in HYPERFINE INTERACTIONS
  • 1996-07. Magnetic properties of microcrystalline iron (III) oxides and related materials as reflected in their Mössbauer spectra in PHYSICS AND CHEMISTRY OF MINERALS
  • 1990-01. Local environment of Gd3+ in MgF2 in PHYSICS AND CHEMISTRY OF MINERALS
  • 1990-07. Some aspects concerning the characterization of iron oxides and hydroxides in soils and clays in HYPERFINE INTERACTIONS
  • 1995-12. Influence of Nonstoichiometry and the Presence of Maghemite on the Mössbauer Spectrum of Magnetite in CLAYS AND CLAY MINERALS
  • 1994-12. Maghemite in basalt studied by Mössbauer spectroscopy in external magnetic field in HYPERFINE INTERACTIONS
  • 1986-02. The effect of the particle morphology on the Mössbauer effect in αFe2O3 in HYPERFINE INTERACTIONS
  • 1998-12. Evidence from Mössbauer spectroscopy of neo-formation of magnetite/maghemite in the soils of loess/paleosol sequences in China in HYPERFINE INTERACTIONS
  • 1994-12. On the methodology of the analysis of Mössbauer spectra in HYPERFINE INTERACTIONS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1023/a:1012603603203

    DOI

    http://dx.doi.org/10.1023/a:1012603603203

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1007943995


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