Reactions of Alkyl 1H,1H-Perfluoroalkyl Sulfones with Ammonia, Amines, and Hydrazines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-05

AUTHORS

V. M. Timoshenko, Ya. V. Nikolin, N. P. Kolesnik, Yu. G. Shermolovich

ABSTRACT

2,2,3,3-Tetrafluoropropyl and 2,2,3,3,4,4,5,5-octafluoropentyl alkyl sulfones react with ammonia, primary and secondary amines, hydrazine hydrate, phenylhydrazine, and N,N-dimethylhydrazine to afford, depending on the length of the polyfluoroalkyl chain and reaction conditions, the corresponding enamines, imines, or mono- and bis-hydrazones. The bis-hydrazone obtained from phenylhydrazine and 2,2,3,3,4,4,5,5-octafluoropentyl benzyl sulfone is capable of undergoing further dehydrofluorination to give 5-difluoromethyl- or 5-unsubstituted 1-phenylpyrazole. More... »

PAGES

624-632

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1012427229154

DOI

http://dx.doi.org/10.1023/a:1012427229154

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030132846


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