Reactions of Methyl 4-Aminofurazan-3-carboximidate with Nitrogen-Containing Nucleophiles View Full Text


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Article Info

DATE

2001-05

AUTHORS

A. V. Sergievskii, S. V. Pirogov, S. F. Mel'nikova, I. V. Tselinskii

ABSTRACT

Methyl 4-aminofurazan-3-carboximidate reacts with aromatic amines and hydrazines to give the corresponding amidines and amidrazones. The reaction of the title compound with o-phenylenediamine yields 3-amino-4-(2-benzimidazolyl)furazan, and with acylhydrazines N2-acyl-4-aminofurazan-3-carbohydrazides are formed. The latter undergo thermal intramolecular cyclization with formation of 3-amino-4-(1,2,4-triazol-3-yl)furazan derivatives containing various substituents in position 5 of the triazole ring. More... »

PAGES

717-720

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1012412220493

DOI

http://dx.doi.org/10.1023/a:1012412220493

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016567523


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